D.K. Kumar
Supramolecular Gel Phase Crystallization: Orthogonal Self-Assembly Under Non-equilibrium Conditions
Kumar, D.K.; Steed, J.W.
Abstract
This tutorial review charts the history of gel phase crystallization from its origins in Liesegang ring formation to current research in the generation of new pharmaceutical solid forms in low molecular weight organogels. The growth of molecular crystals under a supersaturation gradient within the same space and timescale as the formation of a gel phase material is placed into context as an example of orthogonal self-assembly. Such multi-component, weakly coupled orthogonal self-assembly processes occurring far from equilibrium represent a powerful conceptual paradigm for generating fascinating emergent behaviour in chemical systems.
Citation
Kumar, D., & Steed, J. (2014). Supramolecular Gel Phase Crystallization: Orthogonal Self-Assembly Under Non-equilibrium Conditions. Chemical Society Reviews, 44, 2080-2088. https://doi.org/10.1039/c3cs60224a
Journal Article Type | Article |
---|---|
Publication Date | Aug 1, 2014 |
Deposit Date | Nov 12, 2013 |
Publicly Available Date | Jan 10, 2014 |
Journal | Chemical Society Reviews |
Print ISSN | 0306-0012 |
Electronic ISSN | 1460-4744 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 44 |
Pages | 2080-2088 |
DOI | https://doi.org/10.1039/c3cs60224a |
Public URL | https://durham-repository.worktribe.com/output/1447364 |
Files
Accepted Journal Article
(651 Kb)
PDF
You might also like
Scrolling in Supramolecular Gels: A Designer’s Guide
(2024)
Journal Article
Pushing Technique Boundaries to Probe Conformational Polymorphism.
(2023)
Journal Article
Metal-based gels: Synthesis, properties, and applications
(2023)
Journal Article
Vapor Sorption and Halogen-Bond-Induced Solid-Form Rearrangement of a Porous Pharmaceutical
(2023)
Journal Article
Highly Thermally Resistant Bisamide Gelators as Pharmaceutical Crystallization Media
(2022)
Journal Article
Downloadable Citations
About Durham Research Online (DRO)
Administrator e-mail: dro.admin@durham.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2025
Advanced Search