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A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions.

Rojo, M.V.; Guetzoyan, L.; Baxendale, I.R.

Authors

M.V. Rojo

L. Guetzoyan



Abstract

An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

Journal Article Type Article
Acceptance Date Dec 2, 2014
Publication Date 2015-02
Deposit Date Feb 27, 2015
Journal Organic and Biomolecular Chemistry
Print ISSN 1477-0520
Electronic ISSN 1477-0539
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 13
Issue 6
Pages 1768-1777
DOI https://doi.org/10.1039/c4ob02376e
Public URL https://durham-repository.worktribe.com/output/1414232