A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions.

Rojo, M.V.; Guetzoyan, L.; Baxendale, I.R.

Abstract

An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

Citation

Rojo, M., Guetzoyan, L., & Baxendale, I. (2015). A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions. Organic and Biomolecular Chemistry, 13(6), 1768-1777. https://doi.org/10.1039/c4ob02376e

• Journal Article Type: Article
• Acceptance Date: Dec 2, 2014
• Publication Date: 2015-02
• Deposit Date: Feb 27, 2015
• Journal: Organic and Biomolecular Chemistry
• Print ISSN: 1477-0520
• Electronic ISSN: 1477-0539
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 13
• Issue: 6
• Pages: 1768-1777
• DOI: https://doi.org/10.1039/c4ob02376e
• Public URL: https://durham-repository.worktribe.com/output/1414232