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Understanding quaternary compound Cu2ZnSnSe4 synthesis by microscopic scale analyses at an identical location

Crossay, A.; Colombara, D.; Melchiorre, M.; Guennou, M.; Mendis, B.G.; Dale, P.J.

Understanding quaternary compound Cu2ZnSnSe4 synthesis by microscopic scale analyses at an identical location Thumbnail


Authors

A. Crossay

D. Colombara

M. Melchiorre

M. Guennou

P.J. Dale



Abstract

The synthesis of multinary compound films from layered precursors is only partially understood. Identical location microscopy resolves the multi-step synthesis of Cu2ZnSnSe4 from metallic stacks on the micron-scale. Large scale metal alloying and the seemingly illogical observation that ZnSe segregates preferentially on locations previously poor of zinc are revealed.

Citation

Crossay, A., Colombara, D., Melchiorre, M., Guennou, M., Mendis, B., & Dale, P. (2016). Understanding quaternary compound Cu2ZnSnSe4 synthesis by microscopic scale analyses at an identical location. Journal of Materials Chemistry C Materials for optical and electronic devices, 4(21), 4626-4629. https://doi.org/10.1039/c6tc01114d

Journal Article Type Article
Acceptance Date Apr 26, 2016
Online Publication Date Apr 27, 2016
Publication Date Jun 7, 2016
Deposit Date May 10, 2016
Publicly Available Date Apr 26, 2017
Journal Journal of Materials Chemistry C Materials for optical and electronic devices
Print ISSN 2050-7526
Electronic ISSN 2050-7534
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 4
Issue 21
Pages 4626-4629
DOI https://doi.org/10.1039/c6tc01114d
Public URL https://durham-repository.worktribe.com/output/1405054