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Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones

Data, P.; Pander, P.; Zassowski, P.; Mimaite, V.; Karon, K.; Lapkowski, M.; Grazulevicius, J.V.; Slepski, P.; Darowicki, K.

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P. Data

P. Zassowski

V. Mimaite

K. Karon

M. Lapkowski

J.V. Grazulevicius

P. Slepski

K. Darowicki


Triphenylamine-based hydrazones were subjected to electropolymerization process that gave well conductive hydrazone based polymers. The first example of polyhydrazone formation during the electrochemical process was shown. The estimation of polymer structure was demonstrated using IR spectroelectrochemistry. The EPR spectroelectrochemistry allowed to explain why in some cases dimer couldn’t be formed. The results of electrochemical, spectroelectrochemical investigation of small molecules, as well as their polymers obtained by electropolymerization, are presented. The comparative study of electropolymerization and doping process by IR, EPR, potentiostatic and potentiodynamic UV-Vis-NIR, DEIS spectroelectrochemical techniques was performed to determine the reaction path, charge carriers and conductivity of polymeric layers.


Data, P., Pander, P., Zassowski, P., Mimaite, V., Karon, K., Lapkowski, M., …Darowicki, K. (2017). Electrochemically Induced Synthesis of Triphenylamine-based Polyhydrazones. Electrochimica Acta, 230, 10-21.

Journal Article Type Article
Acceptance Date Jan 20, 2017
Online Publication Date Jan 22, 2017
Publication Date Mar 10, 2017
Deposit Date Jul 24, 2017
Publicly Available Date Jul 31, 2017
Journal Electrochimica Acta
Print ISSN 0013-4686
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 230
Pages 10-21


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