Jamie L. Manson
Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system
Manson, Jamie L.; Schlueter, John A.; Garrett, Kerry E.; Goddard, Paul A.; Lancaster, Tom; Möller, Johannes S.; Blundell, Stephen J.; Steele, Andrew J.; Franke, Isabel; Pratt, Francis L.; Singleton, John; Bendix, Jesper; Lapidus, Saul H.; Uhlarz, Marc; Ayala-Valenzuela, Oscar; McDonald, Ross D.; Gurak, Mary; Baines, Christopher
Authors
John A. Schlueter
Kerry E. Garrett
Paul A. Goddard
Professor Tom Lancaster tom.lancaster@durham.ac.uk
Professor
Johannes S. Möller
Stephen J. Blundell
Andrew J. Steele
Isabel Franke
Francis L. Pratt
John Singleton
Jesper Bendix
Saul H. Lapidus
Marc Uhlarz
Oscar Ayala-Valenzuela
Ross D. McDonald
Mary Gurak
Christopher Baines
Abstract
The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n− octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.
Citation
Manson, J. L., Schlueter, J. A., Garrett, K. E., Goddard, P. A., Lancaster, T., Möller, J. S., …Baines, C. (2016). Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 − x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system. Chemical Communications, 52(85), 12653-12656. https://doi.org/10.1039/c6cc05873f
Journal Article Type | Article |
---|---|
Acceptance Date | Sep 27, 2016 |
Online Publication Date | Sep 27, 2016 |
Publication Date | Nov 4, 2016 |
Deposit Date | Oct 18, 2016 |
Publicly Available Date | Sep 27, 2017 |
Journal | Chemical Communications |
Print ISSN | 1359-7345 |
Electronic ISSN | 1364-548X |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 52 |
Issue | 85 |
Pages | 12653-12656 |
DOI | https://doi.org/10.1039/c6cc05873f |
Public URL | https://durham-repository.worktribe.com/output/1374286 |
Files
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(543 Kb)
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