Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts

Patel, N.C.D.; Oliva-Enrich, J.M.; Fox, M.A.

doi:10.1002/ejic.201700419

Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts

Patel, N.C.D.; Oliva-Enrich, J.M.; Fox, M.A.

Authors

N.C.D. Patel

J.M. Oliva-Enrich

Dr Mark Fox m.a.fox@durham.ac.uk
Assistant Professor

Abstract

While geometries of 12- and 13-vertex dicarbaborane (carborane) radicals with rare 2n+3 skeletal electrons have been determined elsewhere, the geometries of the 11-vertex dicarbaborane monoanion radicals with 2n+3 SE are established here for the first time by computations in agreement with observed electrochemical and electron paramagnetic resonance spectroscopy (EPR) data.

Citation

Patel, N., Oliva-Enrich, J., & Fox, M. (2017). Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts. European Journal of Inorganic Chemistry, 2017(38-39), 4568-4574. https://doi.org/10.1002/ejic.201700419

Journal Article Type	Article
Acceptance Date	May 31, 2017
Online Publication Date	Jul 5, 2017
Publication Date	Jul 5, 2017
Deposit Date	Jun 6, 2017
Publicly Available Date	Jul 5, 2018
Journal	European Journal of Inorganic Chemistry
Print ISSN	1434-1948
Electronic ISSN	1099-0682
Publisher	Wiley-VCH Verlag
Peer Reviewed	Peer Reviewed
Volume	2017
Issue	38-39
Pages	4568-4574
DOI	https://doi.org/10.1002/ejic.201700419
Public URL	https://durham-repository.worktribe.com/output/1357761

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Copyright Statement
This is the peer reviewed version of the following article: Fox, Mark A., Patel, Natasha C. D. & Oliva-Enrich, Josep M. (2017). Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts. European Journal of Inorganic Chemistry, which has been published in final form at https://doi.org/10.1002/ejic.201700419. This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for self-archiving.