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Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+binding

Isla, Helena; Srebro-Hooper, Monika; Jean, Marion; Vanthuyne, Nicolas; Roisnel, Thierry; Lunkley, Jamie L.; Muller, Gilles; Williams, J.A. Gareth; Autschbach, Jochen; Crassous, Jeanne

Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+binding Thumbnail


Authors

Helena Isla

Monika Srebro-Hooper

Marion Jean

Nicolas Vanthuyne

Thierry Roisnel

Jamie L. Lunkley

Gilles Muller

Jochen Autschbach

Jeanne Crassous



Abstract

The molecular conformation of a bis-helicenic terpyridine system is strongly modified upon binding to Zn(II) ion, a process that is accompanied by large changes in the optical and chiroptical properties. This system affords a new type of helicene-based chiroptical switching.

Citation

Isla, H., Srebro-Hooper, M., Jean, M., Vanthuyne, N., Roisnel, T., Lunkley, J. L., …Crassous, J. (2016). Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+binding. Chemical Communications, 52(35), 5932-5935. https://doi.org/10.1039/c6cc01748g

Journal Article Type Article
Acceptance Date Mar 24, 2016
Online Publication Date Mar 25, 2016
Publication Date Mar 25, 2016
Deposit Date May 30, 2017
Publicly Available Date Jun 30, 2017
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 52
Issue 35
Pages 5932-5935
DOI https://doi.org/10.1039/c6cc01748g

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