L. Eberlin
A Dienyl Boronate‐Aryl Nitroso Ene Reaction Entry to C‐Pyrrolyl Nitrones and Subsequent Conversion to Isoxazolidines
Eberlin, L.; Macé, A.; Batsanov, A.S.; Carboni, B.; Whiting, A.
Authors
Abstract
A new cascade reaction to access C‐pyrrolyl nitrones en route to isoxazolidines is reported; a process that involves four successive steps, the first key step being an ene‐reaction of a 3‐methyl‐1,3‐dienylboronate ester with an aryl nitroso compounds to derive uncommon 1,3‐dipoles which react with various alkenes to access isoxazolidines. The scope and mechanism of the cascade sequence is discussed.
Citation
Eberlin, L., Macé, A., Batsanov, A., Carboni, B., & Whiting, A. (2018). A Dienyl Boronate‐Aryl Nitroso Ene Reaction Entry to C‐Pyrrolyl Nitrones and Subsequent Conversion to Isoxazolidines. ChemistrySelect, 3(16), 4557-4561. https://doi.org/10.1002/slct.201800945
Journal Article Type | Article |
---|---|
Acceptance Date | Apr 26, 2018 |
Online Publication Date | Apr 25, 2018 |
Publication Date | Apr 30, 2018 |
Deposit Date | Apr 27, 2018 |
Publicly Available Date | Apr 25, 2019 |
Journal | ChemistrySelect |
Electronic ISSN | 2365-6549 |
Publisher | Wiley |
Peer Reviewed | Peer Reviewed |
Volume | 3 |
Issue | 16 |
Pages | 4557-4561 |
DOI | https://doi.org/10.1002/slct.201800945 |
Public URL | https://durham-repository.worktribe.com/output/1332401 |
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Copyright Statement
This is the peer reviewed version of the following article: Eberlin, L., Macé, A., Batsanov, A. S., Carboni, B. & Whiting, A. (2018). A Dienyl Boronate‐Aryl Nitroso Ene Reaction Entry to C‐Pyrrolyl Nitrones and Subsequent Conversion to Isoxazolidines. ChemistrySelect 3(16): 4557-4561, which has been published in final form at https://doi.org/10.1002/slct.201800945. This article may be used for non-commercial purposes in accordance With Wiley-VCH Terms and Conditions for self-archiving.
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