Thermally Activated Delayed Fluorescence with Narrow Emission Spectrum and Organic Room Temperature Phosphorescence by Controlling Spin-Orbit Coupling and Phosphorescence Lifetime of Metal-Free Organic Molecules

Pander, Piotr Henryk; Swist, Agnieszka; Soloducho, Jadwiga; Dias, Fernando; Data, Przemyslaw

Abstract

This work shows a study of two organic molecules with very similar, large singlet-triplet gap of which one is a TADF emitter and the other an RTP emitter. By investigation of photophysical properties of these compounds, it is possible to explain their distinct behavior. Properties are studied in non-polar polymer and OLED host with further device fabrication. Furthermore, this work presents a CT TADF emitter that shows narrow and resolved electroluminescence (FWHM of 53 nm). The study presents efficient RTP emitter based on the D-D-D structure and also a first acridone-based TADF emitter of D-A-D structure.

Citation

Pander, P. H., Swist, A., Soloducho, J., Dias, F., & Data, P. (2018). Thermally Activated Delayed Fluorescence with Narrow Emission Spectrum and Organic Room Temperature Phosphorescence by Controlling Spin-Orbit Coupling and Phosphorescence Lifetime of Metal-Free Organic Molecules. Journal of Materials Chemistry C Materials for optical and electronic devices, 6(20), 5434--5443. https://doi.org/10.1039/c8tc00175h

• Journal Article Type: Article
• Acceptance Date: Apr 13, 2018
• Online Publication Date: Apr 16, 2018
• Publication Date: May 1, 2018
• Deposit Date: Apr 27, 2018
• Publicly Available Date: Apr 13, 2019
• Journal: Journal of Materials Chemistry C Materials for optical and electronic devices
• Print ISSN: 2050-7526
• Electronic ISSN: 2050-7534
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 6
• Issue: 20
• Pages: 5434--5443
• DOI: https://doi.org/10.1039/c8tc00175h