A solid-supported arylboronic acid catalyst for direct amidation

Du, Yihao; Barber, Thomas; Lim, Sol Ee; Rzepa, Henry S.; Baxendale, Ian R.; Whiting, Andrew

Abstract

An efficient heterogeneous amidation catalyst has been prepared by co-polymerisation of styrene, DVB with 4-styreneboronic acid, which shows wide substrate applicability and higher reactivity than the equivalent homogeneous phenylboronic acid, suggesting potential cooperative catalytic effects. The catalyst can be easily recovered and reused; suitable for use in packed bed flow reactors.

Citation

Du, Y., Barber, T., Lim, S. E., Rzepa, H. S., Baxendale, I. R., & Whiting, A. (2019). A solid-supported arylboronic acid catalyst for direct amidation. Chemical Communications, 55(20), 2916-2919. https://doi.org/10.1039/c8cc09913h

• Journal Article Type: Article
• Acceptance Date: Feb 13, 2019
• Online Publication Date: Feb 13, 2019
• Publication Date: Mar 11, 2019
• Deposit Date: Feb 20, 2019
• Publicly Available Date: Feb 13, 2020
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 55
• Issue: 20
• Pages: 2916-2919
• DOI: https://doi.org/10.1039/c8cc09913h
• Public URL: https://durham-repository.worktribe.com/output/1302640