Effect of Diagenesis on Geomechanical Properties of Organic‐rich Calcareous Shale: A Multiscale Investigation

Charlton, T.S.; Goodarzi, M.; Rouainia, M.; Aplin, A.C.; Cubillas, P.

Abstract

This paper investigates the nano to core-scale geomechanical properties of a maturity series of organic-rich, calcareous shales buried to 100-180°C, with a focus on: (a) the mechanical properties of organic matter; (b) the elastic response and anisotropy of the shale composite at micro and core scale; and (c) the creep response. Atomic force microscopy was used to target kerogen at nanoscale resolution, and it was found that the elastic stiffness increased with thermal maturity from 5.8 GPa in an immature sample to 11.3 GPa in a mature sample. Nanoindentation testing of the shale matrix showed that diagenesis is a key factor in determining the bulk elasticity, with increasingly intense carbonate cementation at higher thermal maturities contributing to a stiffer response. A multiscale model was formulated to upscale the elastic properties from nanoscale solid clay minerals to a microcracked composite at core scale, with good predictions of the micro and core-scale stiffness in comparison to indentation and triaxial results. A negative correlation was found between the creep modulus and clay/kerogen content, with greater creep displacement observed in nanoindentation tests in the immature clay- and kerogen-rich sample compared to samples of higher thermal maturity.

Citation

Charlton, T., Goodarzi, M., Rouainia, M., Aplin, A., & Cubillas, P. (2021). Effect of Diagenesis on Geomechanical Properties of Organic‐rich Calcareous Shale: A Multiscale Investigation. Journal of Geophysical Research. Solid Earth, 126(7), Article e2020JB021365. https://doi.org/10.1029/2020jb021365

• Journal Article Type: Article
• Acceptance Date: Jun 8, 2021
• Online Publication Date: Jun 10, 2021
• Publication Date: Jun 30, 2021
• Deposit Date: Jun 13, 2021
• Publicly Available Date: Jul 16, 2021
• Journal: Journal of Geophysical Research: Solid Earth
• Print ISSN: 2169-9313
• Electronic ISSN: 2169-9356
• Publisher: American Geophysical Union
• Peer Reviewed: Peer Reviewed
• Volume: 126
• Issue: 7
• Article Number: e2020JB021365
• DOI: https://doi.org/10.1029/2020jb021365
• Public URL: https://durham-repository.worktribe.com/output/1247121