Outputs (4)

Thermally Activated Delayed Fluorescence: Polarity, Rigidity, and Disorder in Condensed Phases (2022)
Journal Article
Phan Huu, D. A., Saseendran, S., Dhali, R., Gomes Franca, L., Stavrou, K., Monkman, A., & Painelli, A. (2022). Thermally Activated Delayed Fluorescence: Polarity, Rigidity, and Disorder in Condensed Phases. Journal of the American Chemical Society, 144(33), 15211 - 15222. https://doi.org/10.1021/jacs.2c05537

We present a detailed and comprehensive picture of the photophysics of thermally activated delayed fluorescence (TADF). The approach relies on a few-state model, parametrized ab initio on a prototypical TADF dye, that explicitly accounts for the nona... Read More about Thermally Activated Delayed Fluorescence: Polarity, Rigidity, and Disorder in Condensed Phases.

Laplace Transform Fitting as a Tool To Uncover Distributions of Reverse Intersystem Crossing Rates in TADF Systems (2022)
Journal Article
Kelly, D., Gomes Franca, L., Stavrou, K., Danos, A., & Monkman, A. P. (2022). Laplace Transform Fitting as a Tool To Uncover Distributions of Reverse Intersystem Crossing Rates in TADF Systems. Journal of Physical Chemistry Letters, 13(30), 6981-6986. https://doi.org/10.1021/acs.jpclett.2c01864

Donor–acceptor (D–A) thermally activated delayed fluorescence (TADF) molecules are exquisitely sensitive to D–A dihedral angle. Although commonly simplified to an average value, these D–A angles nonetheless exist as distributions across the individua... Read More about Laplace Transform Fitting as a Tool To Uncover Distributions of Reverse Intersystem Crossing Rates in TADF Systems.

Delayed Fluorescence by Triplet–Triplet Annihilation from Columnar Liquid Crystal Films (2022)
Journal Article
Gomes Franca, L., dos Santos, P. L., Pander, P., Cabral, M. G., Cristiano, R., Cazati, T., …Eccher, J. (2022). Delayed Fluorescence by Triplet–Triplet Annihilation from Columnar Liquid Crystal Films. ACS Applied Electronic Materials, 4(7), https://doi.org/10.1021/acsaelm.2c00432

Delayed fluorescence (DF) by triplet–triplet annihilation (TTA) is observed in solutions of a benzoperylene-imidoester mesogen that shows a hexagonal columnar mesophase at room temperature in the neat state. A similar benzoperylene-imide with a sligh... Read More about Delayed Fluorescence by Triplet–Triplet Annihilation from Columnar Liquid Crystal Films.

Spiro donor–acceptor TADF emitters: naked TADF free from inhomogeneity caused by donor acceptor bridge bond disorder. Fast rISC and invariant photophysics in solid state hosts (2022)
Journal Article
Gomes Franca, L., Danos, A., & Monkman, A. (2022). Spiro donor–acceptor TADF emitters: naked TADF free from inhomogeneity caused by donor acceptor bridge bond disorder. Fast rISC and invariant photophysics in solid state hosts. Journal of Materials Chemistry C Materials for optical and electronic devices, 10(4), 1313-1325. https://doi.org/10.1039/d1tc04484b

We have studied the thermally activated delayed fluorescence (TADF) properties of the spiro-bridged donor–acceptor molecule, 10-phenyl-10H,10′H-spiro[acridine-9,9-anthracen]-10′-one, (ACRSA) in guest–host films and used it as a probe to explore the d... Read More about Spiro donor–acceptor TADF emitters: naked TADF free from inhomogeneity caused by donor acceptor bridge bond disorder. Fast rISC and invariant photophysics in solid state hosts.