Dr Juan Aguilar Malavia's Outputs (2)

Dual phosphorescent emissions from conformers of iridium complex rotors. (2024)
Journal Article
Hsu, Y.-T., Bhagani, C., Aguilar, J. A., Fox, M. A., Yufit, D., Davidson, R., & Beeby, A. (2024). Dual phosphorescent emissions from conformers of iridium complex rotors. Dalton Transactions, 53(43), 17518-17524. https://doi.org/10.1039/D4DT02321H

The chiral iridium rotors Ir(ppy)2(pyX)Cl (X = C≡C-SiR3, R= alkyl) remarkably contain two distinct rotational conformers in the ground (S0) and excited (T1) states that can be detected by NMR and emission measurements respectively at variable tempera... Read More about Dual phosphorescent emissions from conformers of iridium complex rotors..

Correlated shapeshifting and configurational isomerization † (2024)
Journal Article
Maturi, W., Hussein, B. A., Rylands, M. K., Bismillah, A. N., Wen, Y., Aguilar, J. A., Ayub, R., Rankine, C. D., & McGonigal, P. R. (online). Correlated shapeshifting and configurational isomerization †. Chemical Science, https://doi.org/10.1039/d4sc03699a

Herein we demonstrate that the rapid ‘shapeshifting’ constitutional isomerization of a substituted bullvalene is influenced by the E-to-Z configurational isomerization of a remote carbamate group, giving rise to correlated motion. We find that, while... Read More about Correlated shapeshifting and configurational isomerization †.