Reactions of iridium and rhodium hydrides with anhydrous HF; crystal structure of [Rh(CO)(PPh3)(3)][BF4].thf
(1998)
Journal Article
Clark, H., Coleman, K., Fawcett, J., Holloway, J., Hope, E., Langer, J., & Smith, I. (1998). Reactions of iridium and rhodium hydrides with anhydrous HF; crystal structure of [Rh(CO)(PPh3)(3)][BF4].thf. Journal of Fluorine Chemistry, 91(2), 207-211. https://doi.org/10.1016/s0022-1139%2898%2900227-9
The reactions of [MH(CO) (PPh3)(3)] (M = Rh or Ir) with anhydrous HF or HBF4. Et2O lead to completely different products. With an excess of acid, when M = Ir, oxidation gives [IrH2(CO) (PPh3)(3)] [X] (X = HF2, BF4), whereas, when M = Rh, dissociation... Read More about Reactions of iridium and rhodium hydrides with anhydrous HF; crystal structure of [Rh(CO)(PPh3)(3)][BF4].thf.