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Professor Karl Coleman's Outputs (3)

Air-stable ruthenium(II) and osmium(II) fluoride complexes. Crystal structures of [OC-6-13][MF2(CO)(2)(PR3)(2)] [M = Ru, PR3 = PEtPh2; M =Os, PR3 = PPh3 or P(C6H11)(3)] (1997)
Journal Article
Coleman, K., Fawcett, J., Holloway, J., Hope, E., & Russell, D. (1997). Air-stable ruthenium(II) and osmium(II) fluoride complexes. Crystal structures of [OC-6-13][MF2(CO)(2)(PR3)(2)] [M = Ru, PR3 = PEtPh2; M =Os, PR3 = PPh3 or P(C6H11)(3)]. Journal of the Chemical Society. Dalton transactions (2001. Online), 3557-3562. https://doi.org/10.1039/a702142i

The reaction of Lewis bases L with [{MF2(CO)(3)}(4)] (M=Ru or Os) in organic solvents provided a clean, high-yield, route to a series of air-and moisture-stable ruthenium(II) and osmium(II) fluoride co-ordination compounds of general formulae [MF2(CO... Read More about Air-stable ruthenium(II) and osmium(II) fluoride complexes. Crystal structures of [OC-6-13][MF2(CO)(2)(PR3)(2)] [M = Ru, PR3 = PEtPh2; M =Os, PR3 = PPh3 or P(C6H11)(3)].

Reaction of ruthenium(II) and osmium(II) hydrides with anhydrous HF (1997)
Journal Article
Coleman, K., Holloway, J., Hope, E., & Langer, J. (1997). Reaction of ruthenium(II) and osmium(II) hydrides with anhydrous HF. Journal of the Chemical Society. Dalton transactions (2001. Online), 4555-4559. https://doi.org/10.1039/a705582j

The reactions of anhydrous HF with the ruthenium(II) and osmium(II) hydride complexes [MH2(CO)(x)(PPh3)(y)] (M = Ru or Os; x = y = 2; x = 1, y = 3) have been studied. For [OC-6-13][MH2(CO)(2)(PPh3)(2)], elimination of dihydrogen affords the previousl... Read More about Reaction of ruthenium(II) and osmium(II) hydrides with anhydrous HF.

Synthesis and characterisation of ruthenium carbonyl fluorides (1997)
Journal Article
Coleman, K., Holloway, J., & Hope, E. (1997). Synthesis and characterisation of ruthenium carbonyl fluorides. Journal of the Chemical Society. Dalton transactions (2001. Online), 1713-1718. https://doi.org/10.1039/a608357i

The oxidative fluorination of [Ru-3(CO)(12)] with XeF2 in anhydrous HF afforded, in solution, cis-[RuF2(CO)(4)] as the major product with [RuF(CO)(5)](+), [Ru2F4(CO)(7)], [{RuF(CO)(4)}(2)(mu-F)](+), mer- and fac-[RuF3(CO)(3)](-), [{RuF2(CO)(3)}(n)] a... Read More about Synthesis and characterisation of ruthenium carbonyl fluorides.