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Dr Andrei Batsanov's Outputs (31)

Synthetic and structural studies on C-ethynyl- and C-bromo-carboranes. (2006)
Journal Article
Fox, M., Cameron, A., Low, P., Paterson, M., Batsanov, A., Goeta, A., …Schirlin, J. (2006). Synthetic and structural studies on C-ethynyl- and C-bromo-carboranes. Dalton Transactions, 29, 3544-3560. https://doi.org/10.1039/b517538k

A high-yield preparation of the C-monoethynyl para-carborane, 1-Me3SiC[triple bond, length as m-dash]C-1,12-C2B10H11, from C-monocopper para-carborane and 1-bromo-2-(trimethylsilyl)ethyne, BrC[triple bond, length as m-dash]CSiMe3 is reported. The low... Read More about Synthetic and structural studies on C-ethynyl- and C-bromo-carboranes..

The interplay of inverted redox potentials and aromaticity in the oxidized states of new pi-electron donors: 9-(1,3-dithiol-2-ylidene)fluorene and 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives. (2006)
Journal Article
Amriou, S., Wang, C., Batsanov, A., Bryce, M., Perepichka, D., Orti, E., …Rovira, C. (2006). The interplay of inverted redox potentials and aromaticity in the oxidized states of new pi-electron donors: 9-(1,3-dithiol-2-ylidene)fluorene and 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives. Chemistry - A European Journal, 12(12), 3389-3400. https://doi.org/10.1002/chem.200501326

Derivatives of 9-(1,3-dithiol-2-ylidene)fluorene (9) and 9-(1,3-dithiol-2-ylidene)thioxanthene (10) have been synthesised using Horner–Wadsworth–Emmons reactions of (1,3-dithiol-2-yl)phosphonate reagents with fluorenone and thioxanthen-9-one. X-ray c... Read More about The interplay of inverted redox potentials and aromaticity in the oxidized states of new pi-electron donors: 9-(1,3-dithiol-2-ylidene)fluorene and 9-(1,3-dithiol-2-ylidene)thioxanthene derivatives..

Fac-Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl) rhodium(III) chloride/bromide dichloromethane benzene solvate. (2006)
Journal Article
Batsanov, A., Marder, T., & Seeler, F. (2006). Fac-Dichlorotris(trimethylphosphine)(trimethylphosphoniomethyl) rhodium(III) chloride/bromide dichloromethane benzene solvate. Acta crystallographica. Section E, 62(3), m574-m575. https://doi.org/10.1107/s1600536806005630

The title complex, [RhCl2(C4H11P)(C3H9P)3](Br0.12/Cl0.88)·CH2Cl2·C6H6, has an ionic structure with fac-octa­hedral coordination of RhIII in the cation. The anion is a mixture of Cl and Br in a 7:1 ratio.

Synthesis, crystal structures, linear and nonlinear optical properties, and theoretical studies of (p-R-phenyl)-, (p-R-phenylethynyl)-, and (E)-[2-(p-R-phenyl)ethenyl]dimesitylboranes and related compounds (2006)
Journal Article
Yuan, Z., Entwistle, C., Collings, J., Albesa-Jove, D., Batsanov, A., Howard, J., …Marder, T. (2006). Synthesis, crystal structures, linear and nonlinear optical properties, and theoretical studies of (p-R-phenyl)-, (p-R-phenylethynyl)-, and (E)-[2-(p-R-phenyl)ethenyl]dimesitylboranes and related compounds. Chemistry - A European Journal, 12(10), 2758-2771. https://doi.org/10.1002/chem.200501096

The (p-R-phenyl)dimesitylboranes (R=Me2N, MeO, MeS, Br, I), (p-R-phenylethynyl)dimesitylboranes (R=Me2N, MeO, MeS, H), (E)-[2-(p-R-phenyl)ethenyl]dimesitylboranes (R=Me2N, H2N, MeO, MeS, H, CN, NO2), (E)-[2-(2-thienyl)ethenyl]dimesitylborane, and (E)... Read More about Synthesis, crystal structures, linear and nonlinear optical properties, and theoretical studies of (p-R-phenyl)-, (p-R-phenylethynyl)-, and (E)-[2-(p-R-phenyl)ethenyl]dimesitylboranes and related compounds.

Arene-perfluoroarene interactions in crystal engineering. Part 14. 1 : 1 Complexes of octafluoronaphthalene with fluorene and 9,10-dihydrophenanthrene (2006)
Journal Article
Collings, J., Batsanov, A., Howard, J., & Marder, T. (2006). Arene-perfluoroarene interactions in crystal engineering. Part 14. 1 : 1 Complexes of octafluoronaphthalene with fluorene and 9,10-dihydrophenanthrene. Canadian Journal of Chemistry, 84(2), 238-242. https://doi.org/10.1139/v06-007

The 1:1 molecular complexes of octafluoronaphthalene (OFN) with fluorene (1) and with 9,10-dihydrophenanthrene (2) were prepared by cocrystallization of the components and characterized by single-crystal X-ray diffraction. The structure of 1 can be d... Read More about Arene-perfluoroarene interactions in crystal engineering. Part 14. 1 : 1 Complexes of octafluoronaphthalene with fluorene and 9,10-dihydrophenanthrene.

Synthesis and reactivity of cobalt boryl complexes. (2006)
Journal Article
Adams, C., Baber, R., Batsanov, A., Bramham, G., Charmant, J., Haddow, M., …Orpen, A. (2006). Synthesis and reactivity of cobalt boryl complexes. Dalton Transactions, 11, 1370-1373. https://doi.org/10.1039/b516594f

The reaction between [Co(PMe3)4] and B2(4-Mecat)2 (4-Mecat = 1,2-O2-4-MeC6H3) or between [Co(PMe2Ph)4] and B2(cat)2 (cat = 1,2-O2C6H4) affords the paramagnetic Co(II) bisboryl complexes [Co(PMe3)3{B(4-Mecat)}2] and [Co(PMe2Ph)3{B(cat)}2] respectively... Read More about Synthesis and reactivity of cobalt boryl complexes..

Convergent synthesis of 10 nm aryleethynylene molecular wires by an iterative regioselective deprotection/sonogashira coupling protocol (2006)
Journal Article
Wang, C., Batsanov, A., & Bryce, M. (2006). Convergent synthesis of 10 nm aryleethynylene molecular wires by an iterative regioselective deprotection/sonogashira coupling protocol. Journal of Organic Chemistry, 71(1), 108-116. https://doi.org/10.1021/jo051711o

The synthesis of a new series of rigid-rod aryleneethynylene derivatives of up to ca. 10 nm molecular length (compounds 16 and 17) is reported using iterative Pd-mediated Sonogashira coupling methodology combined with regioselective removal of the di... Read More about Convergent synthesis of 10 nm aryleethynylene molecular wires by an iterative regioselective deprotection/sonogashira coupling protocol.

Preparative and structural studies on sulfur-linked carborane icosahedra: 2-phenyl-ortho-carboranyl-sulfur systems (2-Ph-1,2-C2B10H10)(2)X (X = S, S-2 or SO), and ortho-carboran-di-yl systems (1,2-C2B10H10Y)(2) (Y = S or SO) (2006)
Journal Article
Batsanov, A., Clegg, W., Copley, R., Fox, M., Gill, W., Grimditch, R., …Wade, K. (2006). Preparative and structural studies on sulfur-linked carborane icosahedra: 2-phenyl-ortho-carboranyl-sulfur systems (2-Ph-1,2-C2B10H10)(2)X (X = S, S-2 or SO), and ortho-carboran-di-yl systems (1,2-C2B10H10Y)(2) (Y = S or SO). Polyhedron, 25(2), 300-306. https://doi.org/10.1016/j.poly.2005.06.046

Details are reported of the preparation and X-ray structural characterisation of the new compounds (PhCbo)2X, where PhCbo = 2-Ph-1,2-C2B10H10 and X = S (1) or SO (3), prepared from PhCboLi and SCl2 or SOCl2 respectively, as well as the known compound... Read More about Preparative and structural studies on sulfur-linked carborane icosahedra: 2-phenyl-ortho-carboranyl-sulfur systems (2-Ph-1,2-C2B10H10)(2)X (X = S, S-2 or SO), and ortho-carboran-di-yl systems (1,2-C2B10H10Y)(2) (Y = S or SO).

Reactions of Icosahedral Carboranes with Iminotris(dimethylamino)Phosphorane HNP(NMe2)3: a Deboronation Intermediate nido-C2B10H12·N(H)P(NMe2)3, Deboronation Reactions and Hydrogen-bonded Closo-carborane Systems (2006)
Journal Article
Batsanov, A. S., Copley, R. C., Davidson, M. G., Fox, M. A., Hibbert, T. G., Howard, J. A., & Wade, K. (2006). Reactions of Icosahedral Carboranes with Iminotris(dimethylamino)Phosphorane HNP(NMe2)3: a Deboronation Intermediate nido-C2B10H12·N(H)P(NMe2)3, Deboronation Reactions and Hydrogen-bonded Closo-carborane Systems. Journal of Cluster Science, 17(1), 119-137. https://doi.org/10.1007/s10876-005-0042-9

Bridged diiridium complexes for electrophosphorescent OLEDs : synthesis, X-ray crystal structures, photophysics, and devices. (2006)
Journal Article
Bettington, S., Tavasli, M., Bryce, M., Batsanov, A., Thompson, A., Al Attar, H., …Monkman, A. (2006). Bridged diiridium complexes for electrophosphorescent OLEDs : synthesis, X-ray crystal structures, photophysics, and devices. Journal of materials chemistry, 16(11), 1046-1052. https://doi.org/10.1039/b515258e

Results are presented which challenge the accepted view that dinuclear transition metal–ligand complexes are unsuitable for organic light-emitting device (OLED) applications due to their low luminescence quantum efficiencies. We establish for the fir... Read More about Bridged diiridium complexes for electrophosphorescent OLEDs : synthesis, X-ray crystal structures, photophysics, and devices..