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Dr Andrei Batsanov's Outputs (2)

Effects of ortho- and para-ring activation on the kinetics of S<sub>N</sub>Ar reactions of 1-chloro-2-nitro and 1-phenoxy-2-nitrobenzenes with aliphatic amines in acetonitrile (2005)
Journal Article
Crampton, M., Emokpae, T., Isanbor, C., Batsanov, A., Howard, J., & Mondal, R. (2006). Effects of ortho- and para-ring activation on the kinetics of SNAr reactions of 1-chloro-2-nitro and 1-phenoxy-2-nitrobenzenes with aliphatic amines in acetonitrile. European Journal of Organic Chemistry, 2006(5), 1222-1230. https://doi.org/10.1002/ejoc.200500774

Rate constants are reported for reaction of 4-substituted 1-chloro-2,6-dinitrobenzenes 1, 6-substituted 1-chloro-2,4-dinitrobenzenes 2, and some of the corresponding 1-phenoxy derivatives, 3 and 4, with n-butylamine, pyrrolidine and piperidine in ace... Read More about Effects of ortho- and para-ring activation on the kinetics of S<sub>N</sub>Ar reactions of 1-chloro-2-nitro and 1-phenoxy-2-nitrobenzenes with aliphatic amines in acetonitrile.

The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands (2005)
Journal Article
Cordiner, R. L., Smith, M. E., Batsanov, A. S., Albesa-Jové, D., Hartl, F., Howard, J. A., & Low, P. J. (2006). The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands. Inorganica Chimica Acta, 359(3), 946-961. https://doi.org/10.1016/j.ica.2005.06.044

The complex [Ru(CCCN)(dppe)Cp*] (1) is readily obtained (ca. 70%) from the sequential reaction of [Ru(CCH2)(dppe)Cp*]PF6 with nBuLi and phenyl cyanate. The complex behaves as a typical transition metal acetylide upon reaction with tetracyanoethene, a... Read More about The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands.