Halogenation of tris(amido)tantalacarboranes with dihalomethanes CH2X2 (X = Cl, Br)
(2002)
Journal Article
Fox, M., Goeta, A., Hughes, A., Malget, J., & Wade, K. (2002). Halogenation of tris(amido)tantalacarboranes with dihalomethanes CH2X2 (X = Cl, Br)
Slow reactions of isomeric metallacarboranes of general formulae [(NMe2)(3)TaC2B9H11] (3 isomers) and [(NMe2)(3) TaC2B9H10Me] (3 isomers) with CD2Cl2 afford quantitative yields of monochloro complexes [Cl(NMe2)(2)TaC2B9H11] and [Cl(NMe2)(2) TaC2B9H10... Read More about Halogenation of tris(amido)tantalacarboranes with dihalomethanes CH2X2 (X = Cl, Br).