In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes
(2023)
Journal Article
Goodall, J. C., Page, S. J., Sajjad, M. A., Thompson, E. A., Kerrigan, A. M., Jenkins, H. T., …Weller, A. S. (2023). In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes. Chemical Communications, 59(72), 10749-10752. https://doi.org/10.1039/d3cc03201a
The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is... Read More about In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes.