All Outputs (2)

Electronic interactions in bridged bis(cluster) assemblies - a comparison of para-CB10H10C, para-C6H4 and C-4 bridges (2005)
Journal Article
Le Guennic, B., Costuas, K., Halet, J., Nervi, C., Paterson, M., Fox, M., …Low, P. (2005). Electronic interactions in bridged bis(cluster) assemblies - a comparison of para-CB10H10C, para-C6H4 and C-4 bridges. Comptes rendus. Chimie, 8(11-12), 1883-1896. https://doi.org/10.1016/j.crci.2005.03.016

The electrochemical response of bis-Co2C2(CO)(4)(mu-dppm) complexes featuring bridging para-CB10H10C (5) and para-C6H4 (6) moieties are similar, each exhibiting two oxidations separated by ca. 100 mV, and two reductions separated by 80 mV, evidencing... Read More about Electronic interactions in bridged bis(cluster) assemblies - a comparison of para-CB10H10C, para-C6H4 and C-4 bridges.

The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands (2005)
Journal Article
Cordiner, R. L., Smith, M. E., Batsanov, A. S., Albesa-Jové, D., Hartl, F., Howard, J. A., & Low, P. J. (2006). The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands. Inorganica Chimica Acta, 359(3), 946-961. https://doi.org/10.1016/j.ica.2005.06.044

The complex [Ru(CCCN)(dppe)Cp*] (1) is readily obtained (ca. 70%) from the sequential reaction of [Ru(CCH2)(dppe)Cp*]PF6 with nBuLi and phenyl cyanate. The complex behaves as a typical transition metal acetylide upon reaction with tetracyanoethene, a... Read More about The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands.