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Amphiphilic Polyurethane with Cluster-Induced Emission for Multichannel Bioimaging in Living Cell Systems. (2023)
Journal Article
Jiang, N., Li, K., Wang, J., Zhu, Y., Zhu, C., Xu, Y., & Bryce, M. R. (2024). Amphiphilic Polyurethane with Cluster-Induced Emission for Multichannel Bioimaging in Living Cell Systems. ACS Macro Letters, 13(1), 52-57. https://doi.org/10.1021/acsmacrolett.3c00657

The development of single-component materials with low cytotoxicity and multichannel fluorescence imaging capability is a research hotspot. In the present work, highly electron-deficient pyrazine monomers were covalently connected into a polyurethane... Read More about Amphiphilic Polyurethane with Cluster-Induced Emission for Multichannel Bioimaging in Living Cell Systems..

Cluster-induced aggregation in polyurethane derivatives with multicolour emission and ultra-long organic room temperature phosphorescence (2023)
Journal Article
Jiang, N., Li, K.-X., Wang, J.-J., Li, C.-S., Xu, X.-Y., Xu, Y.-H., & Bryce, M. R. (2024). Cluster-induced aggregation in polyurethane derivatives with multicolour emission and ultra-long organic room temperature phosphorescence. Journal of Materials Chemistry C Materials for optical and electronic devices, 12(3), 1040-1046. https://doi.org/10.1039/d3tc04141g

Non-conjugated luminescent polymers (NCLPs) have the advantages of simple synthesis, optical tunability, and excellent processability. However, the underlying luminous mechanism in NCLPs remains obscure and it is a considerable challenge to obtain NC... Read More about Cluster-induced aggregation in polyurethane derivatives with multicolour emission and ultra-long organic room temperature phosphorescence.

Structural Diversity in Cyclometalated Diiridium(III) Complexes with Bridging syn and anti μ2‐Oxamidato and μ2‐Dithioxamidato Ligands (2023)
Journal Article
M'hamedi, A., Batsanov, A. S., Fox, M. A., Aguilar, J. A., & Bryce, M. R. (2023). Structural Diversity in Cyclometalated Diiridium(III) Complexes with Bridging syn and anti μ2‐Oxamidato and μ2‐Dithioxamidato Ligands. European Journal of Inorganic Chemistry, 26(34), Article e202300423. https://doi.org/10.1002/ejic.202300423

Six new diiridium complexes containing 2-methyl-6-phenylpyridyl as the cyclometalating ligand with a μ2-oxamidato or a μ2-dithioxamidato ligand as the bridge have been synthesized in 60–73 % yields. These complexes were revealed by multinuclear NMR s... Read More about Structural Diversity in Cyclometalated Diiridium(III) Complexes with Bridging syn and anti μ2‐Oxamidato and μ2‐Dithioxamidato Ligands.

Multicolor Luminescence of a Polyurethane Derivative Driven by Heat/Light-Induced Aggregation (2023)
Journal Article
Jiang, N., Li, K., Xie, W., Zhang, S., Li, X., Hu, Y., …Bryce, M. R. (2023). Multicolor Luminescence of a Polyurethane Derivative Driven by Heat/Light-Induced Aggregation. Macromolecules, 56(19), 7721-7728. https://doi.org/10.1021/acs.macromol.3c01345

The study of aggregate formation and its controllable effect on luminescence behavior has a far-reaching influence in establishing a universal aggregation photophysical mechanism. In this paper, we obtained clusters with different extents of aggregat... Read More about Multicolor Luminescence of a Polyurethane Derivative Driven by Heat/Light-Induced Aggregation.

Near-Infrared Afterglow ONOO–-Triggered Nanoparticles for Real-Time Monitoring and Treatment of Early Ischemic Stroke (2023)
Journal Article
Zhang, L., Wang, Y.-C., Liao, Y., Zhang, Q., Liu, X., Zhu, D., Feng, H., Bryce, M. R., & Ren, L. (2023). Near-Infrared Afterglow ONOO–-Triggered Nanoparticles for Real-Time Monitoring and Treatment of Early Ischemic Stroke. ACS Applied Materials and Interfaces, 15(39), https://doi.org/10.1021/acsami.3c08033

Early detection and drug intervention with the appropriate timing and dosage are the main clinical challenges for ischemic stroke (IS) treatment. The conventional therapeutic agents relay fluorescent signals, which require real-time external light ex... Read More about Near-Infrared Afterglow ONOO–-Triggered Nanoparticles for Real-Time Monitoring and Treatment of Early Ischemic Stroke.

Electronic Conductance and Thermopower of Cross-Conjugated and Skipped-Conjugated Molecules in Single-Molecule Junctions (2023)
Journal Article
Salthouse, R. J., Hurtado-Gallego, J., Grace, I. M., Davidson, R., Alshammari, O., Agraït, N., …Bryce, M. R. (2023). Electronic Conductance and Thermopower of Cross-Conjugated and Skipped-Conjugated Molecules in Single-Molecule Junctions. Journal of Physical Chemistry C, 127(28), 13751-13758. https://doi.org/10.1021/acs.jpcc.3c00742

We report a combined experimental and theoretical study of a series of thiomethyl (SMe) anchored cross-conjugated molecules featuring an acyclic central bridging ketone and their analogous skipped-conjugated alcohol derivatives. Studies of these mole... Read More about Electronic Conductance and Thermopower of Cross-Conjugated and Skipped-Conjugated Molecules in Single-Molecule Junctions.

Full thermoelectric characterization of a single molecule (2023)
Journal Article
Gemma, A., Tabatabaei, F., Drechsler, U., Zulji, A., Dekkiche, H., Mosso, N., …Gotsmann, B. (2023). Full thermoelectric characterization of a single molecule. Nature Communications, 14(1), Article 3868. https://doi.org/10.1038/s41467-023-39368-7

Molecules are predicted to be chemically tunable towards high thermoelectric efficiencies and they could outperform existing materials in the field of energy conversion. However, their capabilities at the more technologically relevant temperature of... Read More about Full thermoelectric characterization of a single molecule.

A review of fused-ring carbazole derivatives as emitter and/or host materials in organic light emitting diode (OLED) applications (2023)
Journal Article
Oner, S., & Bryce, M. R. (2023). A review of fused-ring carbazole derivatives as emitter and/or host materials in organic light emitting diode (OLED) applications. Materials Chemistry Frontiers, 7(19), 4304–4338. https://doi.org/10.1039/d3qm00399j

This review focuses on fused-ring carbazole derivatives, their molecular design, electronic and photophysical properties, and in particular their applications as the emitter and/or the host material in the emitting layer of organic light emitting dio... Read More about A review of fused-ring carbazole derivatives as emitter and/or host materials in organic light emitting diode (OLED) applications.

Oxidation State Tuning of Room Temperature Phosphorescence and Delayed Fluorescence in Phenothiazine and Phenothiazine‐5,5‐dioxide Dimers (2023)
Journal Article
Wright, I. A., Etherington, M. K., Batsanov, A. S., Monkman, A. P., & Bryce, M. R. (2023). Oxidation State Tuning of Room Temperature Phosphorescence and Delayed Fluorescence in Phenothiazine and Phenothiazine‐5,5‐dioxide Dimers. Chemistry - A European Journal, 29(30), Article e202300428. https://doi.org/10.1002/chem.202300428

Heterocyclic dimers consisting of combinations of butterfly-shaped phenothiazine (PTZ) and its chemically oxidized form phenothiazine-5,5-dioxide (PTZ(SO2)) have been synthesized. A twist is imposed across the dimers by ortho-substituents including m... Read More about Oxidation State Tuning of Room Temperature Phosphorescence and Delayed Fluorescence in Phenothiazine and Phenothiazine‐5,5‐dioxide Dimers.

Planar aromatic anchors control the electrical conductance of gold|molecule|graphene junctions (2023)
Journal Article
O’Driscoll, L. J., Jay, M., Robinson, B. J., Sadeghi, H., Wang, X., Penhale-Jones, B., Bryce, M. R., & Lambert, C. J. (2023). Planar aromatic anchors control the electrical conductance of gold|molecule|graphene junctions. Nanoscale Advances, 5(8), 2299-2306. https://doi.org/10.1039/d2na00873d

The synthesis of a family of alkanethiol molecules with planar aromatic head groups, designed to anchor molecules effectively to graphene electrodes, is reported. Characterisation of self-assembled monolayers of these molecules on a gold surface via... Read More about Planar aromatic anchors control the electrical conductance of gold|molecule|graphene junctions.

Self-assembled nanoparticles based on cationic mono-/AIE tetra-nuclear Ir(III) complexes: long wavelength absorption/near-infrared emission photosensitizers for photodynamic therapy (2023)
Journal Article
Wang, Z., Li, L., Wang, W., Wang, R., Li, G., Bian, H., Zhu, D., & Bryce, M. R. (2023). Self-assembled nanoparticles based on cationic mono-/AIE tetra-nuclear Ir(III) complexes: long wavelength absorption/near-infrared emission photosensitizers for photodynamic therapy. Dalton Transactions, 52(6), 1595-1601. https://doi.org/10.1039/d2dt03809a

Cyclometalated Ir(III) complexes as photosensitizers (PSs) have attracted widespread attention because of their good photostability and efficient 1O2 production ability. However, their strong absorption in the UV-vis region severely limits their appl... Read More about Self-assembled nanoparticles based on cationic mono-/AIE tetra-nuclear Ir(III) complexes: long wavelength absorption/near-infrared emission photosensitizers for photodynamic therapy.