All Outputs (4)

Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex (2008)
Journal Article
Smith, M. E., Flynn, E. L., Fox, M. A., Trottier, A., Wrede, E., Yufit, D. S., Howard, J. A., Ronayne, K. L., Towrie, M., Parker, A. W., Hartl, F., & Low, P. J. (2008). Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex. Chemical Communications, 2008(44), 5845-5847. https://doi.org/10.1039/b811357b

Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}(μ-C[triple bond, length as m-dash]CC[triple bond, length as m-dash]N){Re(CO)3(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculat... Read More about Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(ii)–Re(i) complex.

Vibrational excitation through tug-of-war inelastic collisions. (2008)
Journal Article
Greaves, S., Wrede, E., Goldberg, N., Zhang, J., Miller, D., & Zare, R. (2008). Vibrational excitation through tug-of-war inelastic collisions. Nature, 454(7200), 88-91. https://doi.org/10.1038/nature07079

Vibrationally inelastic scattering is a fundamental collision process that converts some of the kinetic energy of the colliding partners into vibrational excitation. The conventional wisdom is that collisions with high impact parameters (where the pa... Read More about Vibrational excitation through tug-of-war inelastic collisions..

New, unexpected, and dominant mechanisms in the hydrogen exchange reaction (2008)
Journal Article
Greaves, S., Murdock, D., Wrede, E., & Althorpe, S. (2008). New, unexpected, and dominant mechanisms in the hydrogen exchange reaction. The Journal of Chemical Physics, 128(16), Article 164306. https://doi.org/10.1063/1.2902972

A quasiclassical trajectory study of the state specific H+D-2(v=0, j=0)-> HD(v'=0, j'=0)+D reaction at a collision energy of 1.85 eV (total energy of 2.04 eV) found that the scattering is governed by two unexpected and dominant new mechanisms, and no... Read More about New, unexpected, and dominant mechanisms in the hydrogen exchange reaction.

A quasiclassical trajectory study of the time-delayed forward scattering in the hydrogen exchange reaction (2008)
Journal Article
Greaves, S., Murdock, D., & Wrede, E. (2008). A quasiclassical trajectory study of the time-delayed forward scattering in the hydrogen exchange reaction. The Journal of Chemical Physics, 128(16), Article 164307. https://doi.org/10.1063/1.2902973

The time-delayed forward scattering mechanism recently identified by Althorpe [Nature (London) 416, 67 (2002)] for the H+D-2(v=0, j=0)-> HD(v'=3, j'=0)+D reaction was analyzed by using quasiclassical trajectory (QCT) methodology. The QCT results were... Read More about A quasiclassical trajectory study of the time-delayed forward scattering in the hydrogen exchange reaction.