Skip to main content

Research Repository

Advanced Search

All Outputs (2)

Diiridium(III) Complexes with Fluorenylpyridyl Cyclometalating and μ 2 ‐Oxamidato Bridging Ligands and their High Efficiency Phosphorescent Solution‐Processed OLEDs (2025)
Journal Article
M'hamedi, A., Fox, M. A., Batsanov, A. S., Al‐Attar, H. A., & Bryce, M. R. (online). Diiridium(III) Complexes with Fluorenylpyridyl Cyclometalating and μ 2 ‐Oxamidato Bridging Ligands and their High Efficiency Phosphorescent Solution‐Processed OLEDs. European Journal of Inorganic Chemistry, Article e202400745. https://doi.org/10.1002/ejic.202400745

Three neutral diiridium(III) complexes with 2‐fluorenylpyridyl (flpy) or 5‐fluoro‐2‐fluorenylpyridyl (flpyF) as C^N cyclometalating ligands and a μ2‐oxamidato bridge have been synthesized. NMR spectroscopy shows that the complexes are inseparable mix... Read More about Diiridium(III) Complexes with Fluorenylpyridyl Cyclometalating and μ 2 ‐Oxamidato Bridging Ligands and their High Efficiency Phosphorescent Solution‐Processed OLEDs.

Structural Diversity in Cyclometalated Diiridium(III) Complexes with Bridging syn and anti μ2‐Oxamidato and μ2‐Dithioxamidato Ligands (2023)
Journal Article
M'hamedi, A., Batsanov, A. S., Fox, M. A., Aguilar, J. A., & Bryce, M. R. (2023). Structural Diversity in Cyclometalated Diiridium(III) Complexes with Bridging syn and anti μ2‐Oxamidato and μ2‐Dithioxamidato Ligands. European Journal of Inorganic Chemistry, 26(34), Article e202300423. https://doi.org/10.1002/ejic.202300423

Six new diiridium complexes containing 2-methyl-6-phenylpyridyl as the cyclometalating ligand with a μ2-oxamidato or a μ2-dithioxamidato ligand as the bridge have been synthesized in 60–73 % yields. These complexes were revealed by multinuclear NMR s... Read More about Structural Diversity in Cyclometalated Diiridium(III) Complexes with Bridging syn and anti μ2‐Oxamidato and μ2‐Dithioxamidato Ligands.