The Interplay of Electronic Configuration and Anion Ordering on the Magnetic Behavior of Hydroxyfluoride Diaspores

Crawford, Catriona; Hiley, Craig; Scott, Cameron; Ritter, Clemens; Lees, Martin; Bristowe, Nicholas; Walton, Richard; Senn, Mark

Abstract

We report a new nickel hydroxyfluoride diaspore Ni(OH)F prepared using hydrothermal synthesis from NiCl ·6H O and NaF. Magnetic characterization reveals that, contrary to other reported transition-metal hydroxyfluoride diaspores, Ni(OH)F displays weak ferromagnetism below the magnetic ordering temperature. To understand this difference, neutron diffraction is used to determine the long-range magnetic structure. The magnetic structure is found to be distinct from those reported for other hydroxyfluoride diaspores and shows an antiferromagnetic spin ordering in which ferromagnetic canting is allowed by symmetry. Furthermore, neutron powder diffraction on a deuterated sample, Ni(OD)F, reveals partial anion ordering that is distinctive to what has previously been reported for Co(OH)F and Fe(OH)F. Density functional theory calculations show that OH/F ordering can have a directing influence on the lowest energy magnetic ground state. Our results point toward a subtle interplay between the sign of magnetic exchange interactions, the electronic configuration, and anion disordering.

Citation

Crawford, C., Hiley, C., Scott, C., Ritter, C., Lees, M., Bristowe, N., …Senn, M. (2024). The Interplay of Electronic Configuration and Anion Ordering on the Magnetic Behavior of Hydroxyfluoride Diaspores. Inorganic Chemistry, 63(20), 9184-9194. https://doi.org/10.1021/acs.inorgchem.4c00679

• Journal Article Type: Article
• Acceptance Date: Apr 30, 2024
• Online Publication Date: May 9, 2024
• Publication Date: May 20, 2024
• Deposit Date: May 8, 2024
• Publicly Available Date: May 14, 2024
• Journal: Inorganic Chemistry
• Print ISSN: 0020-1669
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 63
• Issue: 20
• Pages: 9184-9194
• DOI: https://doi.org/10.1021/acs.inorgchem.4c00679
• Public URL: https://durham-repository.worktribe.com/output/2434744