Cocrystals of 2-(2,4,5,7-tetranitrofluoren-9- ylidene)propanedinitrile and 2,4,5,7-tetranitrofluoren-9-one with chlorobenzene

Batsanov, A.S.; Perepichka, I.F.; Bryce, M.R.; Howard, J.A.K.

Abstract

Crystallization of 2,4,5,7-tetranitro-9- (dicyanomethylene)fluorene [DTeF; systematic name: 2-(2,4,5,7- tetranitro-fluorene-9-ylidene)propanedinitrile] and 2,4,5,7- tetranitrofluoren-9-one (TeNF) from chlorobenzene in the presence of pi -donor compounds yielded the chlorobenzene solvate, C16H4N6O8.C6H5Cl, and the bis(chlorobenzene) solvate, C13H4N4O9. 2C(6)H(5)Cl, respectively. Both structures comprise mixed stacks of twisted fluorene moieties interspersed with nearly parallel chlorobenzene molecules. Solvent-free crystals of DTeF and TeNF were obtained from pure chlorobenzene.

Citation

Batsanov, A., Perepichka, I., Bryce, M., & Howard, J. (2001). Cocrystals of 2-(2,4,5,7-tetranitrofluoren-9- ylidene)propanedinitrile and 2,4,5,7-tetranitrofluoren-9-one with chlorobenzene. Acta crystallographica. Section C, Crystal structure communications, 57, 1299-1302

• Journal Article Type: Article
• Publication Date: 2001-11
• Journal: Acta Crystallographica C: Crystal Structure Communications
• Print ISSN: 0108-2701
• Electronic ISSN: 1600-5759
• Publisher: International Union of Crystallography
• Peer Reviewed: Peer Reviewed
• Volume: 57
• Pages: 1299-1302
• Public URL: https://durham-repository.worktribe.com/output/1588386
• Publisher URL: <Go to ISI>://000172102300026