Synthesis and characterisation of [OC-6-33][OsCl2(CO)(2)L-2](L=phosphine). Crystal structure of [OC-6-33][OsCl2(CO)(2)(PEt3)(2)]

Clark, HCS; Coleman, KS; Fawcett, J; Holloway, JH; Hope, EG; Redding, J; Russell, DR

Abstract

A series of [OC-6-33][OsCl2(CO)(2)L-2] (L = phosphine) complexes have been prepared by cleavage of [OsCl(mu-Cl)(CO)(3)](2) with a variety of phosphines for a comparison of spectroscopic data with those for the related [OC-6-33][OsF2(CO)(2)L-2] (L = phosphine). The X-ray structural characterisation of [OC-6-33] [OsCl2(CO)(2)(PEt3)(2)] represents the first structural characterisation for this class of complex. (C) 1999 Elsevier Science Ltd. All rights reserved.

Citation

Clark, H., Coleman, K., Fawcett, J., Holloway, J., Hope, E., Redding, J., & Russell, D. (1999). Synthesis and characterisation of [OC-6-33][OsCl2(CO)(2)L-2](L=phosphine). Crystal structure of [OC-6-33][OsCl2(CO)(2)(PEt3)(2)]. Polyhedron, 18(8-9), 1207-1210

• Journal Article Type: Article
• Publication Date: 1999
• Journal: Polyhedron
• Print ISSN: 0277-5387
• Electronic ISSN: 1873-3719
• Publisher: Elsevier
• Peer Reviewed: Peer Reviewed
• Volume: 18
• Issue: 8-9
• Pages: 1207-1210
• Keywords: osmium(II) complexes; carbonyl; phosphine; crystal structureFLUORIDE COMPLEXES
• Public URL: https://durham-repository.worktribe.com/output/1576340