Chelating N-pyrrolylphosphino-N-arylaldimine ligands : synthesis, ligand behaviour and applications in catalysis.

Anderson, C.E.; Batsanov, A.S.; Dyer, P.W.; Fawcett, J.; Howard, J.A.K.

Abstract

Two families of variously-substituted N-pyrrolylphosphino-N′-arylaldimine ligands, 2-(aryl–N[double bond, length as m-dash]CH)C4H3N–PR2 {3a–d R = Ph; 4a–d R = Pri2N}, have been prepared from the corresponding pyrrolylaldimines 2. The donor characteristics/basicity of P–N-chelating 3 and 4 have been assessed using a combination of 31P{1H} NMR and IR spectroscopies through study of the magnitudes of 1JSeP for the phosphorus(V) selenides 7 and 8, and measurement of νCO for the complexes [RhCl(CO)(3,4-κ2-P,N)] (5, 6), respectively. The synthesis of the palladium(II) complexes [PdCl2(3,4-κ2-P,N)] (9, 10) was readily achieved from reaction of 3 or 4 with [PdCl2(MeCN)2] in CH2Cl2. X-Ray crystallographic studies of 13d and 14b confirm the chelating nature of the P–N ligands, which adopt a distorted ‘envelope’ conformation, and highlight the potentially significant steric demands of these metal scaffolds. Reaction of equimolar quantities of 3 with [NiBr2(DME)] in MeCN afforded [NiBr2(3-κ2-P,N)] (15), while the same reaction undertaken in CH2Cl2 with 3c gave rise to the homoleptic bis(pyrrolatoimine) derivative [Ni{2-(mes–N[double bond, length as m-dash]CH)C4H3N}2] (16) in 45% yield, following P–N bond cleavage. Complex 16c was characterised in the solid-state by X-ray crystallography. No identifiable metal-containing complexes could be obtained on reaction of 4 with a variety of sources of Ni(II). The palladium dichloride complexes 13 and 14 proved inactive in combination with MAO or EtAlCl2 for ethylene polymerisation, and with methanesulfonic acid for CO/ethylene co-polymerisation. Contrastingly, the nickel complexes 15 in combination with 4.5 eq. EtAlCl2 catalysed the formation of butenes and hexenes with moderate activity from ethylene at 1 bar.

Citation

Anderson, C., Batsanov, A., Dyer, P., Fawcett, J., & Howard, J. (2006). Chelating N-pyrrolylphosphino-N-arylaldimine ligands : synthesis, ligand behaviour and applications in catalysis. Dalton Transactions, 45, 5362-5378. https://doi.org/10.1039/b611652c

• Journal Article Type: Article
• Publication Date: 2006
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 45
• Pages: 5362-5378
• DOI: https://doi.org/10.1039/b611652c
• Public URL: https://durham-repository.worktribe.com/output/1574745