Polyhalogenated heterocyclic compounds. Macrocycles from perfluoro-4-isopropylpyridine

Chambers, R.D.; Hoskin, P.R.; Kenwright, A.R.; Khalil, A.; Richmond, P.; Sandford, G.; Yufit, D.S.; Howard, J.A.K.

Abstract

Perfluoro-4-isopropylpyridine was used as a building block for the two-step synthesis of a variety of macrocyclic systems bearing pyridine sub-units which were characterised by X-ray crystallography. Electrospray mass spectrometry revealed that complexation of either cations and, unusually, anions is possible depending on the structure of the macrocycle.

Citation

Chambers, R., Hoskin, P., Kenwright, A., Khalil, A., Richmond, P., Sandford, G., …Howard, J. (2003). Polyhalogenated heterocyclic compounds. Macrocycles from perfluoro-4-isopropylpyridine. Organic and Biomolecular Chemistry, 1(12), 2137-2147. https://doi.org/10.1039/b303443g

• Journal Article Type: Article
• Publication Date: May 1, 2003
• Deposit Date: Jan 9, 2009
• Journal: Organic and Biomolecular Chemistry
• Print ISSN: 1477-0520
• Electronic ISSN: 1477-0539
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 1
• Issue: 12
• Pages: 2137-2147
• DOI: https://doi.org/10.1039/b303443g
• Public URL: https://durham-repository.worktribe.com/output/1570321