X.J. Zhu
Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans- (PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H
Zhu, X.J.; Ward, R.M.; Albesa-Jove, D.; Howard, J.A.K.; Porres, L.; Beeby, A.; Low, P.J.; Wong, W.K.; Marder, T.B.
Authors
R.M. Ward
D. Albesa-Jove
J.A.K. Howard
L. Porres
Professor Andrew Beeby andrew.beeby@durham.ac.uk
Professor
P.J. Low
W.K. Wong
T.B. Marder
Abstract
Terminal alkynes (R–Ctriple bond; length of mdashC–H, R = 1-naphthyl, 9-anthryl, 4-Me2N–C6H4–, or the longer analogue, 4-(4-Me2N–C6H4–Ctriple bond; length of mdashC–)–C6H4–) react with [Rh(PMe3)4Me] at ambient temperature, with loss of methane and one PMe3 ligand, to form the corresponding mer,trans-[(PMe3)3Rh(Ctriple bond; length of mdashCR)2H] compounds in excellent yield. In this preliminary study, the synthesis and spectroscopic characterization of the four new compounds are reported, along with the single-crystal structure of the R = 4-Me2N–C6H4 derivative.
Citation
Zhu, X., Ward, R., Albesa-Jove, D., Howard, J., Porres, L., Beeby, A., …Marder, T. (2006). Synthesis of new mer,trans-rhodium(III) hydrido-bis(acetylide) complexes: Structure of mer,trans- (PMe3)(3)Rh(C equivalent to C-C6H4-4-NMe2)(2)H. Inorganica Chimica Acta, 359(9), 2859-2863. https://doi.org/10.1016/j.ica.2005.11.030
Journal Article Type | Article |
---|---|
Publication Date | 2006-06 |
Journal | Inorganica Chimica Acta |
Print ISSN | 0020-1693 |
Publisher | Elsevier |
Peer Reviewed | Peer Reviewed |
Volume | 359 |
Issue | 9 |
Pages | 2859-2863 |
DOI | https://doi.org/10.1016/j.ica.2005.11.030 |
Keywords | Acetylide, Alkynyl, Luminescent, Hydride, Crystal structure. |
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