ELECTROCHEMICAL PROPERTIES OF HEXADECANOYLTETRATHIAFULVALENE LANGMUIR-BLODGETT-FILMS

Goldenberg, LM; Cooke, G; Pearson, C; Monkman, AP; Bryce, MR; Petty, MC

Abstract

The electrochemical behaviour of monolayer and multilayer films of hexadecanoyltetrathiafulvalene, deposited on conductive substrates by the Langmuir-Blodgett technique, has been studied by cyclic voltammetry, chronoamperometry and visible/infrared spectroscopy. Monolayer films show stable reversible oxidation to the cation-radical state. However, in thicker structures, the electrochemical response is strongly distorted because of the hindered diffusion of ions.

Citation

Goldenberg, L., Cooke, G., Pearson, C., Monkman, A., Bryce, M., & Petty, M. (1994). ELECTROCHEMICAL PROPERTIES OF HEXADECANOYLTETRATHIAFULVALENE LANGMUIR-BLODGETT-FILMS. Thin Solid Films, 238(2), 280-284

• Journal Article Type: Article
• Publication Date: 1994-02
• Journal: Thin Solid Films
• Print ISSN: 0040-6090
• Publisher: Elsevier
• Volume: 238
• Issue: 2
• Pages: 280-284
• Keywords: CHEMICALLY MODIFIED ELECTRODES