J.A. Ioppolo
Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane
Ioppolo, J.A.; Bhadbhade, M.; Fox, M.A.; Rendina, L.M.
Abstract
Deboronation and cage rearrangement of the closo-1,12-carborane salt [1,12-(PPh2Me)2-1,12-C2B10H10]I2 occurs in refluxing methanol to give the zwitterionic nido-7,9-carborane 7,9-(PPh2Me)2-7,9-C2B9H9. Notably, deboronation and cage substitution of the isomeric closo-1,7-carborane salt [1,7-(PPh2Me)2-1,7-C2B10H10]I2 takes place in methanol to afford the salt [10-OMe-7,9-(PPh2Me)2-7,9-C2B9H9]I.
Citation
Ioppolo, J., Bhadbhade, M., Fox, M., & Rendina, L. (2013). Remarkable cage deboronation and rearrangement of a closo-1,12-dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane. Chemical Communications, 49(32), 3312-3314. https://doi.org/10.1039/c3cc41173g
Journal Article Type | Article |
---|---|
Publication Date | Apr 25, 2013 |
Deposit Date | May 2, 2013 |
Publicly Available Date | Aug 4, 2014 |
Journal | Chemical Communications |
Print ISSN | 1359-7345 |
Electronic ISSN | 1364-548X |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 49 |
Issue | 32 |
Pages | 3312-3314 |
DOI | https://doi.org/10.1039/c3cc41173g |
Public URL | https://durham-repository.worktribe.com/output/1486204 |
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