An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

Moussa, J.; Cheminel, T.; Freeman, G.R.; Chamoreau, L.M.; Williams, J.A.G.; Amouri, H.

Abstract

The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations.

Citation

Moussa, J., Cheminel, T., Freeman, G., Chamoreau, L., Williams, J., & Amouri, H. (2014). An unprecedented cyclometallated platinum(II)complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour. Dalton Transactions, 43(22), 8162-8165. https://doi.org/10.1039/c4dt00589a

• Journal Article Type: Article
• Acceptance Date: Mar 14, 2014
• Online Publication Date: Mar 14, 2014
• Publication Date: Jun 14, 2014
• Deposit Date: Jul 1, 2014
• Publicly Available Date: Jul 8, 2014
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 43
• Issue: 22
• Pages: 8162-8165
• DOI: https://doi.org/10.1039/c4dt00589a
• Public URL: https://durham-repository.worktribe.com/output/1426867