Chris M. Ainsworth
Synthesis, Structural Characterization, and Physical Properties of the New Transition Metal Oxyselenide Ce2O2ZnSe2
Ainsworth, Chris M.; Wang, Chun-Hai; Tucker, Matthew G.; Evans, John S.O.
Abstract
We report the synthesis and characterization of the new oxyselenide Ce2O2ZnSe2, which contains fluorite-like [Ce2O2]2+ layers of Ce4O tetrahedra (red) alternating with anti-fluorite-like [ZnSe2]2− layers (blue). The Zn ordering pattern in the selenide layers is novel yet closely related to those of other divalent transition metal containing compounds. Ce2O2ZnSe2 contains both edge- and corner-sharing ZnSe4 tetrahedra, leading to alternating “checkerboard-like” and “stripe-like” regions along the a axis.
Citation
Ainsworth, C. M., Wang, C., Tucker, M. G., & Evans, J. S. (2015). Synthesis, Structural Characterization, and Physical Properties of the New Transition Metal Oxyselenide Ce2O2ZnSe2. Inorganic Chemistry, 54(4), 1563-1571. https://doi.org/10.1021/ic502551n
| Journal Article Type | Article |
|---|---|
| Publication Date | Feb 16, 2015 |
| Deposit Date | May 4, 2015 |
| Publicly Available Date | May 5, 2015 |
| Journal | Inorganic Chemistry |
| Print ISSN | 0020-1669 |
| Electronic ISSN | 1520-510X |
| Publisher | American Chemical Society |
| Peer Reviewed | Peer Reviewed |
| Volume | 54 |
| Issue | 4 |
| Pages | 1563-1571 |
| DOI | https://doi.org/10.1021/ic502551n |
Files
Accepted Journal Article
(1.6 Mb)
PDF
Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © 2015 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/ic502551n.
You might also like
Solid State Materials Chemistry
(2021)
Book
Structure Analysis from Powder Diffraction Data: Rietveld Refinement in Excel
(2020)
Journal Article