Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications.

Evans, Nicholas H.; Carr, Rachel; Delbianco, Martina; Pal, Robert; Yufit, Dmitry S.; Parker, David

Abstract

Mono-C-substitution of the 1,4,7-triazacyclononane ring induces formation of single enantiomers of Eu(III) complexes with nonadentate N6O3 ligands. The absolute configuration of each complex is determined by the stereogenicity of the C-substituent, revealed by comparison of the sign and sequence of CPL transitions for a series of complexes.

Citation

Evans, N. H., Carr, R., Delbianco, M., Pal, R., Yufit, D. S., & Parker, D. (2013). Complete stereocontrol in the synthesis of macrocyclic lanthanide complexes: direct formation of enantiopure systems for circularly polarised luminescence applications. Dalton Transactions, 42(44), 15610-6. https://doi.org/10.1039/c3dt52425f

• Journal Article Type: Article
• Acceptance Date: Sep 9, 2013
• Online Publication Date: Sep 13, 2013
• Publication Date: 2013-11
• Deposit Date: Mar 17, 2017
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 42
• Issue: 44
• Pages: 15610-6
• DOI: https://doi.org/10.1039/c3dt52425f
• Public URL: https://durham-repository.worktribe.com/output/1361197