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Cation disorder and phase transitions in the structurally complex solar cell material Cu2ZnSnS4

Bosson, C.J.; Birch, M.T.; Halliday, D.P.; Knight, K.S.; Gibbs, A.S.; Hatton, P.D.

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Authors

C.J. Bosson

M.T. Birch

K.S. Knight

A.S. Gibbs



Abstract

Cu2ZnSnS4 (CZTS) is a technologically important and complex quaternary semiconductor and a highly promising material for the absorber layer in sustainable thin film solar cells. Its photovoltaic performance is currently limited by low open-circuit voltage, thought to be due to a range of point defects such as disorder between the copper and zinc lattice sites. This is the highest-resolution neutron diffraction study reported for CZTS, which unambiguously identifies the crystal symmetry and accurately quantifies precise values for the disorder on all cation symmetry sites as a function of temperature. Two samples of CZTS were fabricated by solid state reaction and their compositions were measured by inductively-coupled plasma mass spectroscopy, which identified significant tin loss during growth, leaving the samples Sn-poor, Cu-rich and Sn-poor, Zn-rich respectively. Both samples were found exclusively to adopt the tetragonal kesterite crystal structure with significant cation disorder, which is investigated in detail over the range 4–1275 K. Importantly, and in contrast to previous reports, the 2a Wyckoff site shows disorder equal to or greater than the 2c site. The order–disorder phase transition was observed at different temperatures for the two compositions, 489 and 501 K respectively, lower than previously reported. The kesterite–sphalerite transition was observed between 1250 and 1275 K for the Sn-poor, Cu-rich sample, significantly higher than previously reported. These results provide new insights into the high levels of disorder present in CZTS and confirm that composition and cation disorder have a significant effect on the phase transition mechanism. This work will enable the development of routes to the fabrication of higher-efficiency photovoltaic devices.

Citation

Bosson, C., Birch, M., Halliday, D., Knight, K., Gibbs, A., & Hatton, P. (2017). Cation disorder and phase transitions in the structurally complex solar cell material Cu2ZnSnS4. Journal of Materials Chemistry A: materials for energy and sustainability, 5(32), 16672-16680. https://doi.org/10.1039/c7ta03603e

Journal Article Type Article
Acceptance Date Jul 18, 2017
Online Publication Date Jul 18, 2017
Publication Date Aug 28, 2017
Deposit Date Jul 31, 2017
Publicly Available Date Jul 18, 2018
Journal Journal of Materials Chemistry A: materials for energy and sustainability
Print ISSN 2050-7488
Electronic ISSN 2050-7496
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 5
Issue 32
Pages 16672-16680
DOI https://doi.org/10.1039/c7ta03603e
Public URL https://durham-repository.worktribe.com/output/1350522

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