Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry

Parker, David; Suturina, Elizaveta; Harnden, Alice; Batsanov, Andrei; Fox, Mark; Mason, Kevin; Vonci, Michele; McInnes, Eric; Chilton, Nicholas

Abstract

In two closely related series of eight‐coordinate lanthanide complexes, a switch in the sign of the dominant ligand field parameter and striking variations in the sign, amplitude and orientation of the main component of the magnetic susceptibility tensor as the Ln3+ ion is permuted conspire to mask modest changes in NMR paramagnetic shifts, but are evident in Yb EPR and Eu emission spectra.

Citation

Parker, D., Suturina, E., Harnden, A., Batsanov, A., Fox, M., Mason, K., Vonci, M., McInnes, E., & Chilton, N. (2019). Unravelling the Complexities of Pseudocontact Shift Analysis in Lanthanide Coordination Complexes of Differing Symmetry. Angewandte Chemie, 131(30), 10936-10400. https://doi.org/10.1002/anie.201906031

• Journal Article Type: Article
• Acceptance Date: May 28, 2019
• Online Publication Date: May 29, 2019
• Publication Date: Jul 31, 2019
• Deposit Date: May 30, 2019
• Publicly Available Date: May 29, 2020
• Journal: Angewandte Chemie
• Print ISSN: 0044-8249
• Electronic ISSN: 1521-3757
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 131
• Issue: 30
• Pages: 10936-10400
• DOI: https://doi.org/10.1002/anie.201906031
• Public URL: https://durham-repository.worktribe.com/output/1329763