Super-colossal uniaxial negative thermal expansion in chloranilic acid pyrazine, CA-Pyz

Liu, Huiyu; Gutmann, Matthias J; Stokes, Harold T.; Campbell, Branton J; Evans, Ivana Radosavljevic; Evans, John S.O.

Abstract

There has been significant recent interest in exploiting the large dimension changes that can occur in molecular materials as a function of temperature, stress or under optical illumination. Here we report the remarkable thermal expansion properties of chloranilic acid pyrazine (CA-Pyz) co-crystals. We show that the compound shows uniaxial negative thermal expansion over a wide temperature range with a linear contraction coefficient as low as (−)1500×10−6 K−1 at 250 K. The corresponding 10% contraction between 200 and 300 K is an order of magnitude larger than in the so-called colossal contraction materials. We adopt a symmetry-inspired approach to describe both the structural changes that occur (using rotational-symmetry modes) and the thermal expansion (using strain modes). This allows an extremely compact description of the phase transition and detailed understanding of its atomic origins. We show how the coupling of primary and secondary strain modes in materials showing extreme expansion and contraction can lead to unusual reversals in the temperature dependence of cell parameters.

Citation

Liu, H., Gutmann, M. J., Stokes, H. T., Campbell, B. J., Evans, I. R., & Evans, J. S. (2019). Super-colossal uniaxial negative thermal expansion in chloranilic acid pyrazine, CA-Pyz. Chemistry of Materials, 31(12), 4514-4523. https://doi.org/10.1021/acs.chemmater.9b01135

• Journal Article Type: Article
• Online Publication Date: May 28, 2019
• Publication Date: Jun 25, 2019
• Deposit Date: May 31, 2019
• Publicly Available Date: Jun 14, 2019
• Journal: Chemistry of Materials
• Print ISSN: 0897-4756
• Electronic ISSN: 1520-5002
• Publisher: American Chemical Society
• Peer Reviewed: Peer Reviewed
• Volume: 31
• Issue: 12
• Pages: 4514-4523
• DOI: https://doi.org/10.1021/acs.chemmater.9b01135
• Public URL: https://durham-repository.worktribe.com/output/1300673