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The role of ring-type structures in nonconventional luminescent polyurethane derivatives (2025)
Journal Article
Zhu, C.-Y., Meng, Y.-J., Xu, Y.-H., Xia, C.-Q., Jiang, N., Xu, J.-W., & Bryce, M. R. (2025). The role of ring-type structures in nonconventional luminescent polyurethane derivatives. Journal of Materials Chemistry C, 13(17), 8523-8530. https://doi.org/10.1039/d5tc00577a

Nonconventional luminescent materials have been extensively studied in recent years. However, the ambiguity of their luminescence mechanism seriously hinders their development and the establishment of detailed structure–activity relationships. Based... Read More about The role of ring-type structures in nonconventional luminescent polyurethane derivatives.

Endogenous Near‐Infrared Chemiluminescence: Imaging‐Guided Non‐Invasive Thrombolysis and Anti‐Inflammation Based on a Heteronuclear Transition Metal Complex (2025)
Journal Article
Wang, Z., Zhu, B., Nie, W., Zhang, L., Xiao, N., Zhang, Q., Wu, Z., Shi, C., Zhu, W., Liu, Q., Zhu, D., Bryce, M. R., Ren, L., & Tang, B. Z. (2025). Endogenous Near‐Infrared Chemiluminescence: Imaging‐Guided Non‐Invasive Thrombolysis and Anti‐Inflammation Based on a Heteronuclear Transition Metal Complex. Advanced Science, 12(19), Article 2501257. https://doi.org/10.1002/advs.202501257

Conventional therapy to treat thrombi (blood clots) has significant limitations: i) inflammation; ii) bleeding side effects; iii) re‐embolisation, and iv) in situ thrombi that are not visible. Here it is reported that Cu2Ir nanoparticles (NPs) with a... Read More about Endogenous Near‐Infrared Chemiluminescence: Imaging‐Guided Non‐Invasive Thrombolysis and Anti‐Inflammation Based on a Heteronuclear Transition Metal Complex.

Electronically Perturbed Vibrational Excitations of the Luminescing Stable Blatter Radical (2025)
Journal Article
Bar-David, J., Daaoub, A., Chen, S., Sibug-Torres, S. M., Rocchetti, S., Kang, G., Davidson, R. J., Salthouse, R. J., Guo, C., Mueller, N. S., Sangtarash, S., Bryce, M. R., Sadeghi, H., Baumberg, J. J., Davidson, R. J., & Baumberg, J. J. (2025). Electronically Perturbed Vibrational Excitations of the Luminescing Stable Blatter Radical. ACS Nano, 19(8), 7650-7660. https://doi.org/10.1021/acsnano.4c09661

Stable radicals are spin-active species with a plethora of proposed applications in fields from energy storage and molecular electronics to quantum communications. However, their optical properties and vibrational modes are so far not well understood... Read More about Electronically Perturbed Vibrational Excitations of the Luminescing Stable Blatter Radical.

Leveraging Tumor Microenvironment to Boost Synergistic Photodynamic Therapy, Ferroptosis Anti‐Tumor Efficiency Based on a Functional Iridium(III) Complex (2025)
Journal Article
Pei, Y., Pan, Y., Zhang, Z., Zhu, J., Sun, Y., Zhang, Q., Zhu, D., Li, G., Bryce, M. R., Wang, D., & Tang, B. Z. (online). Leveraging Tumor Microenvironment to Boost Synergistic Photodynamic Therapy, Ferroptosis Anti‐Tumor Efficiency Based on a Functional Iridium(III) Complex. Advanced Science, Article 2413879. https://doi.org/10.1002/advs.202413879

The tumor microenvironment (TME) severely limits the efficacy of clinical applications of photodynamic therapy (PDT). The development of a functional agent allowing full use of the TME to boost synergistic PDT and ferroptosis anti‐tumor efficiency is... Read More about Leveraging Tumor Microenvironment to Boost Synergistic Photodynamic Therapy, Ferroptosis Anti‐Tumor Efficiency Based on a Functional Iridium(III) Complex.

Diiridium(III) Complexes with Fluorenylpyridyl Cyclometalating and μ 2 ‐Oxamidato Bridging Ligands and their High Efficiency Phosphorescent Solution‐Processed OLEDs (2025)
Journal Article
M'hamedi, A., Fox, M. A., Batsanov, A. S., Al‐Attar, H. A., & Bryce, M. R. (2025). Diiridium(III) Complexes with Fluorenylpyridyl Cyclometalating and μ 2 ‐Oxamidato Bridging Ligands and their High Efficiency Phosphorescent Solution‐Processed OLEDs. European Journal of Inorganic Chemistry, 28(6), Article e202400745. https://doi.org/10.1002/ejic.202400745

Three neutral diiridium(III) complexes with 2‐fluorenylpyridyl (flpy) or 5‐fluoro‐2‐fluorenylpyridyl (flpyF) as C^N cyclometalating ligands and a μ2‐oxamidato bridge have been synthesized. NMR spectroscopy shows that the complexes are inseparable mix... Read More about Diiridium(III) Complexes with Fluorenylpyridyl Cyclometalating and μ 2 ‐Oxamidato Bridging Ligands and their High Efficiency Phosphorescent Solution‐Processed OLEDs.

Disulfide-Bridged Cationic Dinuclear Ir(III) Complex with Aggregation-Induced Emission and Glutathione-Consumption Properties for Elevating Photodynamic Therapy (2024)
Journal Article
Huang, M., Cui, J., Wu, Q., Liu, S., Zhu, D., Li, G., Bryce, M. R., Wang, D., & Tang, B. Z. (2024). Disulfide-Bridged Cationic Dinuclear Ir(III) Complex with Aggregation-Induced Emission and Glutathione-Consumption Properties for Elevating Photodynamic Therapy. Inorganic Chemistry, 63(50), 24030-24040. https://doi.org/10.1021/acs.inorgchem.4c04571

The ability of photosensitizers (PSs) to generate reactive oxygen species (ROS) is crucial for photodynamic therapy (PDT). However, many traditional PSs face the drawbacks that aggregation-caused quenching (ACQ) and highly expressed glutathione (GSH)... Read More about Disulfide-Bridged Cationic Dinuclear Ir(III) Complex with Aggregation-Induced Emission and Glutathione-Consumption Properties for Elevating Photodynamic Therapy.

Nonconventional Full-Color Luminescent Polyurethanes: Luminescence Mechanism at the Molecular Orbital Level (2024)
Journal Article
Jiang, N., Meng, Y.-J., Pu, X., Zhu, C.-Y., Tan, S.-H., Xu, Y.-H., Zhu, Y.-L., Xu, J.-W., & Bryce, M. R. (2025). Nonconventional Full-Color Luminescent Polyurethanes: Luminescence Mechanism at the Molecular Orbital Level. Materials Letters, 7(1), 24-31. https://doi.org/10.1021/acsmaterialslett.4c02100

The study of structure–activity relationships is a top priority in the development of nontraditional luminescent materials. In this work, nonconjugated polyurethanes (PUs) with full-color emission (red, green, and blue) are easily obtained by control... Read More about Nonconventional Full-Color Luminescent Polyurethanes: Luminescence Mechanism at the Molecular Orbital Level.

Rigid and planar π-conjugated molecules leading to long-lived intramolecular charge-transfer states exhibiting thermally activated delayed fluorescence (2024)
Journal Article
Kuila, S., Miranda-Salinas, H., Eng, J., Li, C., Bryce, M. R., Penfold, T. J., & Monkman, A. P. (2024). Rigid and planar π-conjugated molecules leading to long-lived intramolecular charge-transfer states exhibiting thermally activated delayed fluorescence. Nature Communications, 15, Article 9611. https://doi.org/10.1038/s41467-024-53740-1

Intramolecular charge transfer (ICT) occurs when photoexcitation causes electron transfer from an electron donor to an electron acceptor within the same molecule and is usually stabilized by decoupling of the donor and acceptor through an orthogonal... Read More about Rigid and planar π-conjugated molecules leading to long-lived intramolecular charge-transfer states exhibiting thermally activated delayed fluorescence.

One-pot preparation of nonconventional luminescent polymer gels driven by polymerization (2024)
Journal Article
Jiang, N., Pu, X., Li, K.-X., Zhu, C.-Y., Sun, Y.-W., Xu, Y.-H., Zhu, Y.-L., & Bryce, M. R. (2024). One-pot preparation of nonconventional luminescent polymer gels driven by polymerization. Polymer Chemistry, 15(40), 4101-4106. https://doi.org/10.1039/d4py00832d

Nonconventional chromophores are good candidates for preparing luminous gels because their luminescence is usually enhanced in the aggregated state. In this work, a simple one-pot strategy for polymerization-induced gelation of polymer fluorescent ge... Read More about One-pot preparation of nonconventional luminescent polymer gels driven by polymerization.

Nonconjugated Polyurethane Derivatives with Aggregation-Induced Luminochromism for Multicolor and White Photoluminescent Films (2024)
Journal Article
Jiang, N., Meng, Y.-J., Zhu, C.-Y., Li, K.-X., Li, X., Xu, Y.-H., Xu, J.-W., & Bryce, M. R. (2024). Nonconjugated Polyurethane Derivatives with Aggregation-Induced Luminochromism for Multicolor and White Photoluminescent Films. ACS Macro Letters, 13(10), 1226-1232. https://doi.org/10.1021/acsmacrolett.4c00534

A simple and effective strategy to obtain solid-state multicolor emitting materials is a particularly attractive topic. Nonconventional/nonconjugated polymers are receiving widespread attention because of their advantages of rich structural diversity... Read More about Nonconjugated Polyurethane Derivatives with Aggregation-Induced Luminochromism for Multicolor and White Photoluminescent Films.