On the role of the counter-ion in defining water structure and dynamics: order, sructure and dynamics in hydrophilic and hydrophobic gadolinium salt complexes
(2006)
Journal Article
Thompson, A., Parker, D., Fulton, D., Howard, J., Pandya, S., Puschmann, H., Senanayake, K., Stenson, P., Badari, A., Botta, M., Avedano, S., & Aime, S. (2006). On the role of the counter-ion in defining water structure and dynamics: order, sructure and dynamics in hydrophilic and hydrophobic gadolinium salt complexes. Dalton Transactions, 2006(47), 5605-5616. https://doi.org/10.1039/b606206g
The crystal structures of the hydrated salts of [Gd.DOTAM]3+ and its more hydrophobic derivative [Gd.2]3+, bearing 4 -phenylethyl groups, (both Gd and Yb salts) are reported and compared. The nature of the anion determines the degree of ordering in t... Read More about On the role of the counter-ion in defining water structure and dynamics: order, sructure and dynamics in hydrophilic and hydrophobic gadolinium salt complexes.