Skip to main content

Research Repository

Advanced Search

Outputs (3)

Thermally Activated Delayed Fluorescence Mediated through the Upper Triplet State Manifold in Non-Charge-Transfer Star-Shaped Triphenylamine–Carbazole Molecules (2018)
Journal Article
Pander, P., Motyka, R., Zassowski, P., Etherington, M. K., Varsano, D., da Silva, T. J., Caldas, M. J., Data, P., & Monkman, A. P. (2018). Thermally Activated Delayed Fluorescence Mediated through the Upper Triplet State Manifold in Non-Charge-Transfer Star-Shaped Triphenylamine–Carbazole Molecules. Journal of Physical Chemistry C, 122(42), 23934-23942. https://doi.org/10.1021/acs.jpcc.8b07610

Thermally activated delayed fluorescence has been found in a group of tricarbazolylamines that are purely electron-donating, non-charge-transfer (CT) molecules. We show that the reverse intersystem crossing step in these materials is mediated through... Read More about Thermally Activated Delayed Fluorescence Mediated through the Upper Triplet State Manifold in Non-Charge-Transfer Star-Shaped Triphenylamine–Carbazole Molecules.

Triphenylamine disubstituted naphthalene diimide: elucidation of excited states involved in TADF and application in near-infrared organic light emitting diodes (2018)
Journal Article
Higginbotham, H. F., Pander, P. H., Rybakiewicz, R., Etherington, M. K., Maniam, S., Zagorska, M., Pron, A., Data, P., & Monkman, A. P. (2018). Triphenylamine disubstituted naphthalene diimide: elucidation of excited states involved in TADF and application in near-infrared organic light emitting diodes. Journal of Materials Chemistry C Materials for optical and electronic devices, 6(30), 8219-8225. https://doi.org/10.1039/c8tc02936a

It is demonstrated that naphthalene diimide core disubstituted with triphenylamine can be used as a Thermally Activated Delayed Fluorescence emitter in Organic Light Emitting Diodes. Detailed spectroscopic studies demonstrated unusual host effects on... Read More about Triphenylamine disubstituted naphthalene diimide: elucidation of excited states involved in TADF and application in near-infrared organic light emitting diodes.

Chemical and conformational control of the energy gaps involved in the thermally activated delayed fluorescence mechanism (2018)
Journal Article
dos Santos, P. L., Etherington, M. K., & Monkman, A. P. (2018). Chemical and conformational control of the energy gaps involved in the thermally activated delayed fluorescence mechanism. Journal of Materials Chemistry C Materials for optical and electronic devices, 6(18), 4842-4853. https://doi.org/10.1039/c8tc00991k

This review summarises the significant developments in our understanding and control of thermally-activated delayed fluorescence (TADF) molecules and the spin–vibronic coupling mechanism, from which we have designed new generations of emitters. It co... Read More about Chemical and conformational control of the energy gaps involved in the thermally activated delayed fluorescence mechanism.