Outputs (5)

Peripheral halogen atoms in multi-resonant thermally activated delayed fluorescence emitters: the role of heavy atoms in intermolecular interactions and spin orbit coupling (2023)
Journal Article
Miranda-Salinas, H., Wang, J., Danos, A., Matulaitis, T., Stavrou, K., Monkman, A. P., & Zysman-Colman, E. (2024). Peripheral halogen atoms in multi-resonant thermally activated delayed fluorescence emitters: the role of heavy atoms in intermolecular interactions and spin orbit coupling. Journal of Materials Chemistry C Materials for optical and electronic devices, 12(6), 1996-2006. https://doi.org/10.1039/d3tc04394k

Multi-resonant thermally activated delayed fluorescence materials (MR-TADF) can show narrow-band emission with high photoluminescence quantum efficiency, desirable for applications in organic light emitting diodes (OLEDS). However, they frequently su... Read More about Peripheral halogen atoms in multi-resonant thermally activated delayed fluorescence emitters: the role of heavy atoms in intermolecular interactions and spin orbit coupling.

Quantifying Molecular Disorder in Tri-Isopropyl Silane (TIPS) Pentacene Using Variable Coherence Transmission Electron Microscopy (2023)
Journal Article
Alanazi, F., Eggeman, A. S., Stavrou, K., Danos, A., Monkman, A. P., & Mendis, B. G. (2023). Quantifying Molecular Disorder in Tri-Isopropyl Silane (TIPS) Pentacene Using Variable Coherence Transmission Electron Microscopy. Journal of Physical Chemistry Letters, 14(36), 8183-8190. https://doi.org/10.1021/acs.jpclett.3c01344

Structural disorder in molecular crystals is a fundamental limitation for achieving high charge carrier mobilities. Quantifying and uncovering the mechanistic origins of disorder are, however, extremely challenging. Here we use variable coherence tra... Read More about Quantifying Molecular Disorder in Tri-Isopropyl Silane (TIPS) Pentacene Using Variable Coherence Transmission Electron Microscopy.

Rational design of dibenzo[a,c]phenazine-derived isomeric thermally activated delayed fluorescence luminophores for efficient orange-red organic light-emitting diodes (2023)
Journal Article
Ye, H., Yang, J., Stavrou, K., Li, M., Liu, F., Li, F., …Monkman, A. P. (2023). Rational design of dibenzo[a,c]phenazine-derived isomeric thermally activated delayed fluorescence luminophores for efficient orange-red organic light-emitting diodes. Dyes and Pigments, 219, Article 111568. https://doi.org/10.1016/j.dyepig.2023.111568

It is an immense challenge to develop efficient long-wavelength (orange-to-red) thermally activated delayed fluorescence (TADF) materials due to the increasing nonradiative decay rates following the energy-gap law. Herein, two pairs of asymmetric iso... Read More about Rational design of dibenzo[a,c]phenazine-derived isomeric thermally activated delayed fluorescence luminophores for efficient orange-red organic light-emitting diodes.

Azaborine as a Versatile Weak Donor for Thermally Activated Delayed Fluorescence (2023)
Journal Article
Sudhakar, P., Kuila, S., Stavrou, K., Danos, A., Slawin, A. M., Monkman, A., & Zysman-Colman, E. (2023). Azaborine as a Versatile Weak Donor for Thermally Activated Delayed Fluorescence. ACS Applied Materials and Interfaces, 15(21), 25806-25818. https://doi.org/10.1021/acsami.3c05409

Extensive research has been devoted to the development of thermally activated delayed fluorescence emitters, especially those showing pure-blue emission for use in lighting and fullcolor display applications. Towards that goal, herein we report a nov... Read More about Azaborine as a Versatile Weak Donor for Thermally Activated Delayed Fluorescence.

Unexpected Quasi‐Axial Conformer in Thermally Activated Delayed Fluorescence DMAC‐TRZ, Pushing Green OLEDs to Blue (2023)
Journal Article
Stavrou, K., Franca, L. G., Böhmer, T., Duben, L. M., Marian, C. M., & Monkman, A. P. (2023). Unexpected Quasi‐Axial Conformer in Thermally Activated Delayed Fluorescence DMAC‐TRZ, Pushing Green OLEDs to Blue. Advanced Functional Materials, 33(25), Article 2300910. https://doi.org/10.1002/adfm.202300910

Hidden photophysics is elucidated in the very well-known thermally activated delayed fluorescence (TADF) emitter, DMAC-TRZ. A molecule that, based on its structure, is considered not to have more than one structural conformation. However, based on ex... Read More about Unexpected Quasi‐Axial Conformer in Thermally Activated Delayed Fluorescence DMAC‐TRZ, Pushing Green OLEDs to Blue.