Outputs (5)

Allophycocyanin A is a carbon dioxide receptor in the cyanobacterial phycobilisome (2022)
Journal Article
Guillen-Garcia, A., Gibson, S., Jordan, C., Ramaswamy, V., Linthwaite, V., Bromley, E., …Cann, M. (2022). Allophycocyanin A is a carbon dioxide receptor in the cyanobacterial phycobilisome. Nature Communications, 13, Article 5289. https://doi.org/10.1038/s41467-022-32925-6

Light harvesting is fundamental for production of ATP and reducing equivalents for CO2 fixation during photosynthesis. However, electronic energy transfer (EET) through a photosystem can harm the photosynthetic apparatus when not balanced with CO2. H... Read More about Allophycocyanin A is a carbon dioxide receptor in the cyanobacterial phycobilisome.

Spectroscopic Determination of an Anion-π Bond Strength (2019)
Journal Article
Anstöter, C. S., Rogers, J. P., & Verlet, J. R. (2019). Spectroscopic Determination of an Anion-π Bond Strength. Journal of the American Chemical Society, 141(15), 6132-6135. https://doi.org/10.1021/jacs.9b01345

The anion-π bond has emerged as an important non-valence interaction in supramolecular and biological structure. Although recognized as a strong non-covalent interaction, driven by electrostatic charge-quadrupole moment and correlation interactions,... Read More about Spectroscopic Determination of an Anion-π Bond Strength.

Photoelectron Spectroscopy of the Hexafluorobenzene Cluster Anions: (C₆F₆)_n⁻ (n = 1 – 5) and I⁻(C₆F₆) (2019)
Journal Article
Rogers, J. P., Anstöter, C. S., Bull, J. N., Curchod, B. F., & Verlet, J. R. (2019). Photoelectron Spectroscopy of the Hexafluorobenzene Cluster Anions: (C₆F₆)n− (n = 1 – 5) and I−(C₆F₆). The Journal of Physical Chemistry A, 123(8), 1602-1612. https://doi.org/10.1021/acs.jpca.8b11627

Frequency-resolved (2D) photoelectron (PE) spectra of the anionic clusters (C6F6)n–, for n = 1–5, and time-resolved PE spectra of I–C6F6 are presented using a newly built instrument and supported by electronic structure calculations. From the 2D PE s... Read More about Photoelectron Spectroscopy of the Hexafluorobenzene Cluster Anions: (C₆F₆)_n⁻ (n = 1 – 5) and I⁻(C₆F₆).

Evidence of Electron Capture of an Outgoing Photoelectron Wave by a Nonvalence State in (C6F6)n– (2018)
Journal Article
Rogers, J. P., Anstöter, C. S., & Verlet, J. R. (2018). Evidence of Electron Capture of an Outgoing Photoelectron Wave by a Nonvalence State in (C6F6)n–. Journal of Physical Chemistry Letters, 9, 2504-2509. https://doi.org/10.1021/acs.jpclett.8b00739

Frequency-resolved photoelectron spectra are presented for (C6F6)n– with n = 1–5 that show that C6F6– is solvated by neutral C6F6 molecules. Direct photodetachment channels of C6F6– are observed for all n, leaving the neutral in the S0 ground state o... Read More about Evidence of Electron Capture of an Outgoing Photoelectron Wave by a Nonvalence State in (C6F6)n–.

Ultrafast dynamics of low-energy electron attachment via a non-valence correlation-bound state (2018)
Journal Article
Rogers, J. P., Anstöter, C. S., & Verlet, J. R. (2018). Ultrafast dynamics of low-energy electron attachment via a non-valence correlation-bound state. Nature Chemistry, 10, 341-346. https://doi.org/10.1038/nchem.2912

The primary electron-attachment process in electron-driven chemistry represents one of the most fundamental chemical transformations with wide-ranging importance in science and technology. However, the mechanistic detail of the seemingly simple react... Read More about Ultrafast dynamics of low-energy electron attachment via a non-valence correlation-bound state.