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Spectroscopic Determination of an Anion-π Bond Strength (2019)
Journal Article
Anstöter, C. S., Rogers, J. P., & Verlet, J. R. (2019). Spectroscopic Determination of an Anion-π Bond Strength. Journal of the American Chemical Society, 141(15), 6132-6135. https://doi.org/10.1021/jacs.9b01345

The anion-π bond has emerged as an important non-valence interaction in supramolecular and biological structure. Although recognized as a strong non-covalent interaction, driven by electrostatic charge-quadrupole moment and correlation interactions,... Read More about Spectroscopic Determination of an Anion-π Bond Strength.

Photoelectron Spectroscopy of the Hexafluorobenzene Cluster Anions: (C₆F₆)<sub>n</sub><sup>−</sup> (n = 1 – 5) and I<sup>−</sup>(C₆F₆) (2019)
Journal Article
Rogers, J. P., Anstöter, C. S., Bull, J. N., Curchod, B. F., & Verlet, J. R. (2019). Photoelectron Spectroscopy of the Hexafluorobenzene Cluster Anions: (C₆F₆)n− (n = 1 – 5) and I−(C₆F₆). The Journal of Physical Chemistry A, 123(8), 1602-1612. https://doi.org/10.1021/acs.jpca.8b11627

Frequency-resolved (2D) photoelectron (PE) spectra of the anionic clusters (C6F6)n–, for n = 1–5, and time-resolved PE spectra of I–C6F6 are presented using a newly built instrument and supported by electronic structure calculations. From the 2D PE s... Read More about Photoelectron Spectroscopy of the Hexafluorobenzene Cluster Anions: (C₆F₆)<sub>n</sub><sup>−</sup> (n = 1 – 5) and I<sup>−</sup>(C₆F₆).