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The Complex Excited-state Behavior of a Polyspirobifluorene Derivative: The Role of Spiroconjugation and Mixed Charge Transfer Character on Excited-state Stabilization and Radiative Lifetime (2008)
Journal Article
Hintschich, S. I., Rothe, C., King, S. M., Clark, S. J., & Monkman, A. P. (2008). The Complex Excited-state Behavior of a Polyspirobifluorene Derivative: The Role of Spiroconjugation and Mixed Charge Transfer Character on Excited-state Stabilization and Radiative Lifetime. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 112(51), 16300-16306. https://doi.org/10.1021/jp8044884

In this study, we report on the unusual fluorescence decay of an alkoxy-substituted polyspirobifluorene. Excited state behavior has been probed as a function of time, using femtosecond photobleaching, single photon counting, and streak camera techniq... Read More about The Complex Excited-state Behavior of a Polyspirobifluorene Derivative: The Role of Spiroconjugation and Mixed Charge Transfer Character on Excited-state Stabilization and Radiative Lifetime.

Enhanced triplet formation by twisted intramolecular charge-transfer excited states in conjugated oligomers and polymers. (2008)
Journal Article
King, S., Matheson, R., Dias, F., & Monkman, A. (2008). Enhanced triplet formation by twisted intramolecular charge-transfer excited states in conjugated oligomers and polymers. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 112(27), 8010-8016. https://doi.org/10.1021/jp712163b

The triplet yield and intersystem crossing rate of a set of conjugated oligomers and polymers that, in polar solvents, form a charge-transfer state with a twisted conformation has been investigated. It was observed that in these dibenzothiophene-fluo... Read More about Enhanced triplet formation by twisted intramolecular charge-transfer excited states in conjugated oligomers and polymers..

Dipolar stabilization of emissive singlet charge transfer excited states in polyfluorene copolymers (2008)
Journal Article
Dias, F., King, S., Monkman, A., Perepichka, I., Kryuchkov, M., Perepichka, I., & Bryce, M. (2008). Dipolar stabilization of emissive singlet charge transfer excited states in polyfluorene copolymers. Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 112(21), 6557-6566. https://doi.org/10.1021/jp800068d

The singlet excited-state dynamics in poly[(9,9-dioctylfluorene)−(dibenzothiophene-S,S-dioxide)] (PFSx) random copolymers with different contents of dibenzothiophene-S,S-dioxide (S) units have been studied by steady-state and time resolved fluorescen... Read More about Dipolar stabilization of emissive singlet charge transfer excited states in polyfluorene copolymers.