Dual phosphorescent emissions from conformers of iridium complex rotors.
(2024)
Journal Article
Hsu, Y.-T., Bhagani, C., Aguilar, J. A., Fox, M. A., Yufit, D., Davidson, R., & Beeby, A. (online). Dual phosphorescent emissions from conformers of iridium complex rotors. Dalton Transactions,
The chiral iridium rotors Ir(ppy)2(pyX)Cl (X = C≡C-SiR3, R= alkyl) remarkably contain two distinct rotational conformers in the ground (S0) and excited (T1) states that can be detected by NMR and emission measurements respectively at variable tempera... Read More about Dual phosphorescent emissions from conformers of iridium complex rotors..