All Outputs (3)

Slow magnetic relaxation in Fe(ii) m-terphenyl complexes (2022)
Journal Article
Valentine, A. J., Geer, A. M., Blundell, T. J., Tovey, W., Cliffe, M. J., Davies, E. S., …Kays, D. L. (2022). Slow magnetic relaxation in Fe(ii) m-terphenyl complexes. Dalton Transactions, 51(47), 18118-18126. https://doi.org/10.1039/d2dt03531f

Two-coordinate transition metal complexes are exciting candidates for single-molecule magnets (SMMs) because their highly axial coordination environments lead to sizeable magnetic anisotropy. We report a series of five structurally related two-coordi... Read More about Slow magnetic relaxation in Fe(ii) m-terphenyl complexes.

Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate (2022)
Journal Article
Blundell, T. J., Morritt, A. L., Rusbridge, E. K., Quibell, L., Oakes, J., Akutsu, H., …Martin, L. (2022). Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate. Materials Advances, 3(11), 4724-4735. https://doi.org/10.1039/d2ma00384h

We present the synthesis, crystal structures and conducting properties of six new BEDT-TTF radical-cation salts with the tris(oxalato)gallate or -iridate anion. The use of halobenzenes gives 4 : 1 β′′ metallic or superconducting salts with tris(oxala... Read More about Molecular conductors from bis(ethylenedithio)tetrathiafulvalene with tris(oxalato)gallate and tris(oxalato)iridate.

Enantiopure and racemic radical-cation salts of B(mandelate)2− and B(2-chloromandelate)2− anions with BEDT-TTF (2022)
Journal Article
Blundell, T. J., Lopez, J. R., Sneade, K., Wallis, J. D., Akutsu, H., Nakazawa, Y., …Martin, L. (2022). Enantiopure and racemic radical-cation salts of B(mandelate)2− and B(2-chloromandelate)2− anions with BEDT-TTF. Dalton Transactions, 51(12), 4843-4852. https://doi.org/10.1039/d2dt00024e

We report the first examples of radical-cation salts of BEDT-TTF with spiroborate anions [B(mandelate)2]− and [B(2-chloromandelate)2]−, synthesized from either enantiopure or racemic bidentate mandelate or chloromandelate ligands. In the salts prepar... Read More about Enantiopure and racemic radical-cation salts of B(mandelate)2− and B(2-chloromandelate)2− anions with BEDT-TTF.