All Outputs (2)

Solid/Gas In Crystallo Reactivity of an Ir(I) Methylidene Complex (2024)
Journal Article
Altus, K. M., Sajjad, M. A., Gyton, M. R., Whitwood, A. C., Page, S. J., Macgregor, S. A., & Weller, A. S. (2024). Solid/Gas In Crystallo Reactivity of an Ir(I) Methylidene Complex. Organometallics, https://doi.org/10.1021/acs.organomet.4c00119

In crystallo stabilization of known, but solution unstable, methylidene complex [Ir(tBu-PONOP)(═CH2)][BArF4] allows single-crystal to single-crystal solid/gas reactivity associated with the {Ir═CH2} group to be studied. Addition of H2 results in [Ir(... Read More about Solid/Gas In Crystallo Reactivity of an Ir(I) Methylidene Complex.

In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes (2023)
Journal Article
Goodall, J. C., Page, S. J., Sajjad, M. A., Thompson, E. A., Kerrigan, A. M., Jenkins, H. T., …Weller, A. S. (2023). In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes. Chemical Communications, 59(72), 10749-10752. https://doi.org/10.1039/d3cc03201a

The group 7 complexes [M(κ3-2,6-(R2PO)2C5H3N)(CO)2L][BArF4] [M = Mn, R = iPr, L = THF; M = Re, R = tBu, L = vacant site] undergo in crystallo solid-gas reactivity with CO to form the products of THF substitution or CO addition respectively. There is... Read More about In crystallo lattice adaptivity triggered by solid-gas reactions of cationic group 7 pincer complexes.