All Outputs (5)

Extended ligand conjugation and dinuclearity as a route to efficient platinum-based near-infrared (NIR) triplet emitters and solution-processed NIR-OLEDs (2020)
Journal Article
Shafikov, M. Z., Pander, P., Zaytsev, A. V., Daniels, R., Martinscroft, R., Dias, F. B., …Kozhevnikov, V. N. (2021). Extended ligand conjugation and dinuclearity as a route to efficient platinum-based near-infrared (NIR) triplet emitters and solution-processed NIR-OLEDs. Journal of Materials Chemistry C Materials for optical and electronic devices, 9(1), 127-135. https://doi.org/10.1039/d0tc04881j

Near infrared (NIR) emission from molecular materials is typically targeted by using more extended conjugated systems compared to visible-emitting materials. But efficiencies usually fall off due to the combined effects of increasing non-radiative an... Read More about Extended ligand conjugation and dinuclearity as a route to efficient platinum-based near-infrared (NIR) triplet emitters and solution-processed NIR-OLEDs.

Benzannulation via the use of 1,2,4-triazines extends aromatic system of cyclometallated Pt(II) complexes to achieve candle light electroluminescence (2020)
Journal Article
Pander, P., Turnbull, G., Zaytsev, A. V., Dias, F. B., & Kozhevnikov, V. N. (2021). Benzannulation via the use of 1,2,4-triazines extends aromatic system of cyclometallated Pt(II) complexes to achieve candle light electroluminescence. Dyes and Pigments, 184, Article 108857. https://doi.org/10.1016/j.dyepig.2020.108857

This work describes an application of 1,2,4-triazine methodology for the synthesis of novel cyclometallated Pt (II) complexes of C^N type. It is shown that addition of a cyclopenteno unit into the complex structure not only facilitates the fabricatio... Read More about Benzannulation via the use of 1,2,4-triazines extends aromatic system of cyclometallated Pt(II) complexes to achieve candle light electroluminescence.

Luminescent halogen-substituted 2-(N-arylimino)pyrrolyl boron complexes: the internal heavy-atom effect (2020)
Journal Article
Rodrigues, A. I., Krishnamoorthy, P., Gomes, C. S., Carmona, N., Di Paolo, R. E., Pander, P., …Gomes, P. T. (2020). Luminescent halogen-substituted 2-(N-arylimino)pyrrolyl boron complexes: the internal heavy-atom effect. Dalton Transactions, 49(29), 10185-10202. https://doi.org/10.1039/d0dt01845g

A group of new boron complexes [BPh2{2N,N’-NC4H3-2-C(H)=N-C6H4X}] (X= 4-Cl 4c, 4-Br 4d, 4-I 4e, 3-Br 4f, 2-Br 4g, 2-I 4h) containing different halogens as substituents in the N-aryl ring have been synthesized and characterized in terms of their mole... Read More about Luminescent halogen-substituted 2-(N-arylimino)pyrrolyl boron complexes: the internal heavy-atom effect.

Toward Efficient Toxic-Gas Detectors: Exploring Molecular Interactions of Sarin and Dimethyl Methylphosphonate with Metal-Centered Phthalocyanine Structures (2020)
Journal Article
Aldahhak, H., Powroźnik, P., Pander, P., Jakubik, W., Dias, F. B., Schmidt, W. G., …Krzywiecki, M. (2020). Toward Efficient Toxic-Gas Detectors: Exploring Molecular Interactions of Sarin and Dimethyl Methylphosphonate with Metal-Centered Phthalocyanine Structures. Journal of Physical Chemistry C, 124(11), 6090-6102. https://doi.org/10.1021/acs.jpcc.9b11116

The rapid and reliable detection of lethal agents such as sarin is of increasing importance. Here, density-functional theory (DFT) is used to compare the interaction of sarin with single-metal-centered phthalocyanine (MPc) and MPc layer structures to... Read More about Toward Efficient Toxic-Gas Detectors: Exploring Molecular Interactions of Sarin and Dimethyl Methylphosphonate with Metal-Centered Phthalocyanine Structures.

Donor-acceptor 1,2,4,5-Tetrazines Prepared by Buchwald-Hartwig Cross-Coupling Reaction and Their Photoluminescence Turn-on Property by Inverse Electron Demand Diels-Alder Reaction (2020)
Journal Article
Qu, Y., Pander, P. H., Vybornyi, O., Vasylieva, M., Guillot, R., Miomandre, F., …Audebert, P. (2020). Donor-acceptor 1,2,4,5-Tetrazines Prepared by Buchwald-Hartwig Cross-Coupling Reaction and Their Photoluminescence Turn-on Property by Inverse Electron Demand Diels-Alder Reaction. Journal of Organic Chemistry, 85(5), 3407-3416. https://doi.org/10.1021/acs.joc.9b02817

A facile efficient synthetic tool, Buchwald-Hartwig cross-coupling reaction, for the functionalization of 1,2,4,5-tetrazines is presented. Important factors affecting the Buchwald-Hartwig cross-coupling reaction have been optimized. Seven new donor-a... Read More about Donor-acceptor 1,2,4,5-Tetrazines Prepared by Buchwald-Hartwig Cross-Coupling Reaction and Their Photoluminescence Turn-on Property by Inverse Electron Demand Diels-Alder Reaction.