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New pi-electron rich donors and cavities and their supramolecular assemblies: Synthesis, electrochemistry and crystal structures (2002)
Journal Article
Bryce, M., Batsanov, A., Godbert, N., & Christensen, C. (2002). New pi-electron rich donors and cavities and their supramolecular assemblies: Synthesis, electrochemistry and crystal structures. Molecular Crystals and Liquid Crystals, 379, 1-8

The synthesis, solution redox properties and X-ray crystal structures of 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene derivatives are described.

New electron-transporting materials for light emitting diodes: 1,3,4-oxadiazole-pyridine and 1,3,4-oxadiazole-pyrimidine hybrids (2002)
Journal Article
Wang, C., Jung, G., Batsanov, A., Bryce, M., & Petty, M. (2002). New electron-transporting materials for light emitting diodes: 1,3,4-oxadiazole-pyridine and 1,3,4-oxadiazole-pyrimidine hybrids. Journal of materials chemistry, 12(2), 173-180

We describe the synthesis of three new isomeric 1,3,4-oxadiazole-pyridine hybrids, namely: 2,6-, 3,5- and 2,4-bis[2-(4-tert-butylphenyl)-1,3,4-oxadiazol-5-yl] pyridine, (PDPy-2,6, PDPy-3,5 and PDPy-2,4, respectively) and a 1,3,4-oxadiazole-pyrimidine... Read More about New electron-transporting materials for light emitting diodes: 1,3,4-oxadiazole-pyridine and 1,3,4-oxadiazole-pyrimidine hybrids.

Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry (2002)
Journal Article
Farren, C., Christensen, C., FitzGerald, S., Bryce, M., & Beeby, A. (2002). Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry. Journal of Organic Chemistry, 67(26), 9130-9139

A number of silicon phthalocyanine bis-esters have been synthesized and characterized, with axial ligands containing one or more tetrathiafulvalene groups. Variations in the substitution positions around a central aromatic "hinge" within the ligands... Read More about Synthesis of novel phthalocyanine-tetrathiafulvalene hybrids; Intramolecular fluorescence quenching related to molecular geometry.

Electrochemically controlled interactions between TTF-based dendrimers and an electron-rich oligomer (2002)
Journal Article
Beeby, A., Bryce, M., Christensen, C., Cooke, G., Duclairoir, F., & Rotello, V. (2002). Electrochemically controlled interactions between TTF-based dendrimers and an electron-rich oligomer. Chemical Communications, 2002(24), 2950-2951. https://doi.org/10.1039/B209765F

Electrochemically controlled interactions have been shown to occur between TTF containing dendrimers 1 and 2 and the electron-rich oligomer 3.

An unexpected TTFAQ donor-fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate (2002)
Journal Article
Batsanov, A., Bryce, M., Lyubchik, S., & Perepichka, I. (2002). An unexpected TTFAQ donor-fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate. Acta crystallographica. Section B, Structural science, 58, O1106-O1110

Reaction of the electron acceptor 2,5,7-trinitro-4-bromo-9-dicyanomethylenefluorene (1) and the electron donor 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylidene)-9,10- dihydroanthracene (2) in dioxane resulted in the formation of a novel typ... Read More about An unexpected TTFAQ donor-fluorene acceptor reaction resulting in a novel salt: 2,6-dihexyloxy-9,10-bis(4,5-dimethyl-1,3-dithiol-2-ylium)-anthracene bis(2,5,7-trinitro-4-bromo-9-cyanofluorenide) dioxane trisolvate.

A blended layer MEH-PPV electroluminescent device incorporating a new electron transport material (2002)
Journal Article
Cea, P., Hua, Y., Pearson, C., Wang, C., Bryce, M., Lopez, M., & Petty, M. (2002). A blended layer MEH-PPV electroluminescent device incorporating a new electron transport material. Materials Science and Engineering: C, 22(1), 87-89

Single layer organic light-emitting devices containing both poly[2-(2-ethylhexyloxy)-5-methoxy-1,4-phenylenevinylene] (MEH-PPV) as an emissive polymer and a new electron transport (ET) material, 2,5-bis[5-(4-tert-butylphenyl)-2-pyridyl]-1,3,4-oxadiaz... Read More about A blended layer MEH-PPV electroluminescent device incorporating a new electron transport material.

Functionalized pyridylboronic acids and their Suzuki cross-coupling reactions to yield novel heteroarylpyridines (2002)
Journal Article
Parry, P., Wang, C., Batsanov, A., Bryce, M., & Tarbit, B. (2002). Functionalized pyridylboronic acids and their Suzuki cross-coupling reactions to yield novel heteroarylpyridines. Journal of Organic Chemistry, 67(21), 7541-7543

2-Bromo-5-pyridylboronic acid 2a, 2-chloro-5-pyridylboronic acid 2b, 2-methoxy-5-pyridylboronic acid 2c, and 5-chloro-2-methoxy-4-pyridylboronic acid 4 have been synthesized and shown to undergo palladium-catalyzed cross-coupling reactions with heter... Read More about Functionalized pyridylboronic acids and their Suzuki cross-coupling reactions to yield novel heteroarylpyridines.

Engineering a remarkably low HOMO-LUMO gap by covalent linkage of a strong π-donor and a π-acceptor-tetrathiafulvalene-σ-polynitrofluorene diads: Their amphoteric redox behavior, electron transfer and spectroscopic properties (2002)
Journal Article
Perepichka, D., Bryce, M., Batsanov, A., McInnes, E., Zhao, J., & Farley, R. (2002). Engineering a remarkably low HOMO-LUMO gap by covalent linkage of a strong π-donor and a π-acceptor-tetrathiafulvalene-σ-polynitrofluorene diads: Their amphoteric redox behavior, electron transfer and spectroscopic properties. Chemistry - A European Journal, 8(20), 4656-4669. https://doi.org/10.1002/1521-3765%2820021018%298%3A20%3C4656%3A%3Aaid-chem4656%3E3.0.co%3B2-1

Novel R3TTF-sigma-A compounds 14, 16 and 19 (R3TTF = trial-kyltetrathiafulvalene, sigma = saturated spacer, A = polynitrofluoren-9-dicyano-methylene acceptor) incorporating very strong donor and acceptor moieties have been synthesized by condensation... Read More about Engineering a remarkably low HOMO-LUMO gap by covalent linkage of a strong π-donor and a π-acceptor-tetrathiafulvalene-σ-polynitrofluorene diads: Their amphoteric redox behavior, electron transfer and spectroscopic properties.

A (π-extended tetrathiafulvalene)-fluorene conjugate. Unusual electrochemistry and charge transfer properties: The first observation of a covalent D²⁺–σ–A˙⁻ redox state (2002)
Journal Article
Perepichka, D., Bryce, M., Perepichka, I., Lyubchik, S., Christensen, C., Godbert, N., …Zhao, J. (2002). A (π-extended tetrathiafulvalene)-fluorene conjugate. Unusual electrochemistry and charge transfer properties: The first observation of a covalent D²⁺–σ–A˙⁻ redox state. Journal of the American Chemical Society, 124(47), 14227-14238. https://doi.org/10.1021/ja012518o

The synthesis of novel electrochemically amphoteric TTFAQ-sigma-A compounds (TTFAQ = 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene, sigma = saturated spacer, A = polynitrofluorene acceptor) is reported. Their solution redox behavior is chara... Read More about A (π-extended tetrathiafulvalene)-fluorene conjugate. Unusual electrochemistry and charge transfer properties: The first observation of a covalent D²⁺–σ–A˙⁻ redox state.

Fluorescent phthalocyanine dimers - a steady state and flash photolysis study (2002)
Journal Article
FitzGerald, S., Farren, C., Stanley, C., Beeby, A., & Bryce, M. (2002). Fluorescent phthalocyanine dimers - a steady state and flash photolysis study. Photochemical & Photobiological Sciences, 1(8), 581-587

Steady state and time resolved studies of a tetrakis[(+/-)-2,2-dimethyl-1,3-dioxan-4-ylmethanol] (solketal) substituted zinc phthalocyanine (1) and its derivatives (4a-c) are reported. These compounds form novel fluorescent dimers (or higher order ag... Read More about Fluorescent phthalocyanine dimers - a steady state and flash photolysis study.

Synthesis of novel chiral bis(ferrocenyl) ligands and their use as voltammetric metal cation sensors (2002)
Journal Article
Sutcliffe, O., Bryce, M., & Batsanov, A. (2002). Synthesis of novel chiral bis(ferrocenyl) ligands and their use as voltammetric metal cation sensors. Journal of Organometallic Chemistry, 656(1-2), 211-216

Bis(ferrocenyl) derivatives 3a, 3c and 3d containing secondary chelating substituents act as efficient voltammetric sensors of Mg2+ and Zn2+ ions in acetonitrile solution in concentrations as low as 10 mol%: a new redox peak appears in the cyclic vol... Read More about Synthesis of novel chiral bis(ferrocenyl) ligands and their use as voltammetric metal cation sensors.

Photophysics of a fluorene co-polymer in solution and films. (2002)
Journal Article
Palsson, L., Wang, C., Russell, D., Monkman, A., Bryce, M., Rumbles, G., & Samuel, I. (2002). Photophysics of a fluorene co-polymer in solution and films. Chemical Physics, 279(2-3), 229-237. https://doi.org/10.1016/s0301-0104%2802%2900407-x

The photophysical properties of a new light-emitting co-polymer of fluorene and di-alkoxyphenylene are reported. A range of optical spectroscopies were applied to both solutions and solid films, and comparing the results gives information about the e... Read More about Photophysics of a fluorene co-polymer in solution and films..

Protonation and subsequent intramolecular hydrogen bonding as a method to control chain structure and tune luminescence in heteroatomic conjugated polymers (2002)
Journal Article
Monkman, A., Pålsson, L., Higgins, R., Wang, C., Bryce, M., Batsanov, A., & Howard, J. (2002). Protonation and subsequent intramolecular hydrogen bonding as a method to control chain structure and tune luminescence in heteroatomic conjugated polymers. Journal of the American Chemical Society, 124(21), 6049-6055. https://doi.org/10.1021/ja012409%2B

We report the effects of protonation on the structural and spectroscopic properties of 1,4-dimethoxy-2,5-bis(2-pyridyl)benzene (9) and the related AB coploymer poly{2,5-pyridylene-co-1,4-[2,5- bis(2-ethylhexyloxy)]phenylene} (7). X-ray crystallograph... Read More about Protonation and subsequent intramolecular hydrogen bonding as a method to control chain structure and tune luminescence in heteroatomic conjugated polymers.

Single layer polymer electroluminescent devices incorporating new electron transport materials (2002)
Journal Article
Cea, P., Hua, Y., Pearson, C., Wang, C., Bryce, M., Royo, F., & Petty, M. (2002). Single layer polymer electroluminescent devices incorporating new electron transport materials. Thin Solid Films, 408(1-2), 275-281

The opto-electronic properties of single layer light emitting devices containing the polymer poly [2-(2-ethylhexyloxy)-5-methoxy-1,4-phenylenevinylene] and different electron transport materials are reported. Two oxadiazole derivatives and three oxad... Read More about Single layer polymer electroluminescent devices incorporating new electron transport materials.

A biosensor for monitoring formaldehyde using a new lipophilic tetrathiafulvalene-tetracyanoquinodimethane salt and a polyurethane membrane (2002)
Journal Article
Kataky, R., Bryce, M., Goldenberg, L., Hayes, S., & Nowak, A. (2002). A biosensor for monitoring formaldehyde using a new lipophilic tetrathiafulvalene-tetracyanoquinodimethane salt and a polyurethane membrane. Talanta, 56(3), 451-458

A format for a disposable screen-printed biosensor was investigated for monitoring formaldehyde. The screen-printed sensor format comprised a working electrode (WE) modified with platinised carbon, a new lipophilic tetrathiafulvalene-tetracyanoquinod... Read More about A biosensor for monitoring formaldehyde using a new lipophilic tetrathiafulvalene-tetracyanoquinodimethane salt and a polyurethane membrane.

Supramolecular architecture of two charge-transfer complexes based on 2,7-(X,X)-4,5-dinitro-9-dicyanomethylenefluorenes (X=NO2 or CN) and tetrathiafulvalene (2002)
Journal Article
Kuz'mina, L., Perepichka, I., Perepichka, D., Howard, J., & Bryce, M. (2002). Supramolecular architecture of two charge-transfer complexes based on 2,7-(X,X)-4,5-dinitro-9-dicyanomethylenefluorenes (X=NO2 or CN) and tetrathiafulvalene. Crystallography Reports, 47(2), 251-261

The crystal packings of two charge-transfer complexes based on tetrathiafulvalene and substituted fluorenes-2,4,5,7-tetranitro-9-dicyanomethylenefluorene (in complex 1) or 2,7-dicyano-4,5-dinitro-9-dicyanomethylenefluorene (in complex II)-are analyze... Read More about Supramolecular architecture of two charge-transfer complexes based on 2,7-(X,X)-4,5-dinitro-9-dicyanomethylenefluorenes (X=NO2 or CN) and tetrathiafulvalene.

The first genuine observation of fluorescent mononuclear phthalocyanine aggregates (2002)
Journal Article
Farren, C., FitzGerald, S., Beeby, A., & Bryce, M. (2002). The first genuine observation of fluorescent mononuclear phthalocyanine aggregates. Chemical Communications, 2002(6), 572-573. https://doi.org/10.1039/B110876J

An initial photophysical study of a tetra-solketal-substituted zinc phthalocyanine is reported; at low temperature this compound exhibits very strong aggregation, and a new red shifted emission peak is observed, lambda(max) approximate to750 nm, attr... Read More about The first genuine observation of fluorescent mononuclear phthalocyanine aggregates.