All Outputs (5)

Polyhedral Carboranes (2007)
Book Chapter
Fox, M. (2007). Polyhedral Carboranes. In D. M. P. Mingos, & R. H. Crabtree (Eds.), Comprehensive Organometallic Chemistry III (49-112). Amsterdam: Elsevier. https://doi.org/10.1016/B0-08-045047-4/00043-1

This chapter covers the syntheses and geometries of polyhedral carboranes. Conversions of C–H and B–H bonds into C–X and B–X, respectively (where X is a nonmetal substituent), in these systems are also discussed. Significant developments described ar... Read More about Polyhedral Carboranes.

Elemental fluorine - Part 20. Direct fluorination of deactivated aromatic systems using microreactor techniques (2007)
Journal Article
Fox, M. (2007). Elemental fluorine - Part 20. Direct fluorination of deactivated aromatic systems using microreactor techniques. Journal of Fluorine Chemistry, 128(1), 29-33. https://doi.org/10.1016/j.jfluchem.2006.09.010

The preparation and characterisation of ruthenium cyanovinylidene complexes. (2007)
Journal Article
Brown, N. J., Eckert, P. K., Fox, M. A., Yufit, D. S., Howard, J. A., & Low, P. J. (2008). The preparation and characterisation of ruthenium cyanovinylidene complexes. Dalton Transactions, 433-436. https://doi.org/10.1039/b714274a

Reactions of half-sandwich ruthenium metal acetylide complexes with 1-cyano-4-dimethylaminopyridinium salts afford complexes containing mono- or di-cyanovinylidene ligands; the procedure can be adapted to permit the simple synthesis of a cyanoacetyli... Read More about The preparation and characterisation of ruthenium cyanovinylidene complexes..

Spectroscopic properties and electronic structures of 17-electron half-sandwich ruthenium acetylide complexes, [Ru(CCAr)(L2)Cp′]+ (Ar=phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2=(PPh3)2, Cp′=Cp; L2=dppe; Cp′=Cp∗). (2007)
Journal Article
Fox, M. A., Roberts, R. L., Khairul, W. M., Hartl, F., & Low, P. J. (2007). Spectroscopic properties and electronic structures of 17-electron half-sandwich ruthenium acetylide complexes, [Ru(CCAr)(L2)Cp′]+ (Ar=phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2=(PPh3)2, Cp′=Cp; L2=dppe; Cp′=Cp∗). Journal of Organometallic Chemistry, 692(15), 3277-3290. https://doi.org/10.1016/j.jorganchem.2007.03.042

A series of half-sandwich bis(phosphine) ruthenium acetylide complexes [Ru(CCAr)(L2)Cp′] (Ar = phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2 = (PPh3)2, Cp′ = Cp; L2 = dppe; Cp′ = Cp∗) have been examined using electrochemical and spectroelectrochemical m... Read More about Spectroscopic properties and electronic structures of 17-electron half-sandwich ruthenium acetylide complexes, [Ru(CCAr)(L2)Cp′]+ (Ar=phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2=(PPh3)2, Cp′=Cp; L2=dppe; Cp′=Cp∗)..

Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count (2007)
Journal Article
Fox, M., Nervi, C., Crivello, A., & Low, P. (2007). Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count. Chemical Communications, 23, 2372-2374. https://doi.org/10.1039/b700110j

One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable carborane radical anion ([1]–) with a true 2n + 3 cluster electron count; the geometry of ([1]–) features an elongated CC cage distance but no signific... Read More about Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count.